Modeling the settling and resuspension of microplastics in rivers: Effect of particle properties and flow conditions.

Microplastics have numerous different shapes, affecting the fate and transport of these particles in the environment. However, theoretical models generally assume microplastics to be spherical. This study aims to develop a modeling approach that incorporates the shapes of microplastics to investigate the vertical transport of microplastics in rivers and simulate the effect of particle and flow characteristics on settling and resuspension. To achieve these aims, a mechanistic model was developed utilizing the mass-balance and hydrodynamic equations. Scenario analysis was implemented assigning different values to model parameters, such as bed shear stress, shape factor and particle size to simulate the effect of flow patterns and particle properties. The model outcomes revealed that the residence time of microplastics in the water column was longest in medium bed shear stress, whilst it was shortest in low bed shear stress. This suggests that the influence of turbulence is not unidirectional; it can both increase and decrease microplastic concentrations and residence time in the water column. According to the scenario analysis, the settling flux of microplastics was the highest for near-spherical particles and increased with the size of the particles, as well as with increasing bed shear stress. However, the resuspension of particles was primarily influenced by increasing bed shear stress, but the ranking of resuspension flux values for different shaped and sized microplastics exhibited alterations with changing flow patterns. Turbulent conditions predominantly influenced the resuspension of near-spheres and large microplastics. On the contrary, the settling of fibers and small microplastics were significantly influenced by changing flow patterns, whereas near-spheres and largest particles were least affected. The model results were sensitive to changes in shape factor developed for this model, therefore this parameter should be improved in future studies.