Subert Rodolfo, Campos-Villalobos Gerardo, Dijkstra Marjolein
Soft Condensed Matter & Biophysics, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 1, 3584 CC, Utrecht, The Netherlands.
International Institute for Sustainability with Knotted Chiral Meta Matter (WPI-SKCM2), Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-Hiroshima, Hiroshima, Japan.
Nat Commun. 2024 Aug 8;15(1):6780. doi: 10.1038/s41467-024-50935-4.
Skyrmions are topologically protected, vortex-like structures found in various condensed-matter systems including helical ferromagnets and liquid crystals, typically arising from chiral interactions. Using extensive particle-based simulations, we demonstrate that non-chiral hard banana-shaped particles, governed solely by excluded-volume interactions, spontaneously stabilize skyrmion structures through the bend-flexoelectric effect. Under thin confinement, we observe the formation of quasi-2D layers of isolated skyrmions or dense skyrmion lattices. These structures, comprising a racemic mixture of left- and right-handed skyrmions, show resilience against thermal fluctuations while remaining responsive to external fields, offering intriguing possibilities for manipulation. We also find that the size of these skyrmions can be adjusted by the dimensions and curvature of the banana-shaped particles. In the absence of geometric frustration due to confinement, a blue phase III may emerge, characterized by a 3D network of chiral skyrmion filaments of the nematic director field within an isotropic background. Our findings provide valuable insights into stabilizing skyrmion lattices and blue phases, showcasing non-Gaussian fluid-like dynamics in systems of achiral hard particles. Furthermore, they highlight the remarkable capacity of these complex fluids in designing advanced functional materials with diverse applications in photonics and memory devices.
斯格明子是拓扑学上受保护的、类似涡旋的结构,存在于包括螺旋铁磁体和液晶在内的各种凝聚态系统中,通常由手性相互作用产生。通过广泛的基于粒子的模拟,我们证明了仅受体积排除相互作用支配的非手性硬香蕉形粒子,通过弯曲 - 挠曲电效应自发地稳定斯格明子结构。在薄约束条件下,我们观察到孤立斯格明子或密集斯格明子晶格的准二维层的形成。这些结构由左旋和右旋斯格明子的外消旋混合物组成,对热涨落具有弹性,同时对外部场保持响应,为操纵提供了有趣的可能性。我们还发现,这些斯格明子的大小可以通过香蕉形粒子的尺寸和曲率来调节。在没有由于约束导致的几何失配的情况下,可能会出现蓝相III,其特征是在各向同性背景内的向列型指向矢场的手性斯格明子细丝的三维网络。我们的研究结果为稳定斯格明子晶格和蓝相提供了有价值的见解,展示了非手性硬粒子系统中类似非高斯流体的动力学。此外,它们突出了这些复杂流体在设计具有光子学和存储设备等多种应用的先进功能材料方面的卓越能力。