• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

非手性硬香蕉组装成双扭曲斯格明子和蓝相。

Achiral hard bananas assemble double-twist skyrmions and blue phases.

作者信息

Subert Rodolfo, Campos-Villalobos Gerardo, Dijkstra Marjolein

机构信息

Soft Condensed Matter & Biophysics, Debye Institute for Nanomaterials Science, Utrecht University, Princetonplein 1, 3584 CC, Utrecht, The Netherlands.

International Institute for Sustainability with Knotted Chiral Meta Matter (WPI-SKCM2), Hiroshima University, 1-3-1 Kagamiyama, 739-8526, Higashi-Hiroshima, Hiroshima, Japan.

出版信息

Nat Commun. 2024 Aug 8;15(1):6780. doi: 10.1038/s41467-024-50935-4.

DOI:10.1038/s41467-024-50935-4
PMID:39117620
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11310516/
Abstract

Skyrmions are topologically protected, vortex-like structures found in various condensed-matter systems including helical ferromagnets and liquid crystals, typically arising from chiral interactions. Using extensive particle-based simulations, we demonstrate that non-chiral hard banana-shaped particles, governed solely by excluded-volume interactions, spontaneously stabilize skyrmion structures through the bend-flexoelectric effect. Under thin confinement, we observe the formation of quasi-2D layers of isolated skyrmions or dense skyrmion lattices. These structures, comprising a racemic mixture of left- and right-handed skyrmions, show resilience against thermal fluctuations while remaining responsive to external fields, offering intriguing possibilities for manipulation. We also find that the size of these skyrmions can be adjusted by the dimensions and curvature of the banana-shaped particles. In the absence of geometric frustration due to confinement, a blue phase III may emerge, characterized by a 3D network of chiral skyrmion filaments of the nematic director field within an isotropic background. Our findings provide valuable insights into stabilizing skyrmion lattices and blue phases, showcasing non-Gaussian fluid-like dynamics in systems of achiral hard particles. Furthermore, they highlight the remarkable capacity of these complex fluids in designing advanced functional materials with diverse applications in photonics and memory devices.

摘要

斯格明子是拓扑学上受保护的、类似涡旋的结构,存在于包括螺旋铁磁体和液晶在内的各种凝聚态系统中,通常由手性相互作用产生。通过广泛的基于粒子的模拟,我们证明了仅受体积排除相互作用支配的非手性硬香蕉形粒子,通过弯曲 - 挠曲电效应自发地稳定斯格明子结构。在薄约束条件下,我们观察到孤立斯格明子或密集斯格明子晶格的准二维层的形成。这些结构由左旋和右旋斯格明子的外消旋混合物组成,对热涨落具有弹性,同时对外部场保持响应,为操纵提供了有趣的可能性。我们还发现,这些斯格明子的大小可以通过香蕉形粒子的尺寸和曲率来调节。在没有由于约束导致的几何失配的情况下,可能会出现蓝相III,其特征是在各向同性背景内的向列型指向矢场的手性斯格明子细丝的三维网络。我们的研究结果为稳定斯格明子晶格和蓝相提供了有价值的见解,展示了非手性硬粒子系统中类似非高斯流体的动力学。此外,它们突出了这些复杂流体在设计具有光子学和存储设备等多种应用的先进功能材料方面的卓越能力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/28d81ca3cbfb/41467_2024_50935_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/11b3b6e775a9/41467_2024_50935_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/25b7cbe027b0/41467_2024_50935_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/609d22aa3c78/41467_2024_50935_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/3a22ff805ab1/41467_2024_50935_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/ffd97192141b/41467_2024_50935_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/0107d0bed111/41467_2024_50935_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/28d81ca3cbfb/41467_2024_50935_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/11b3b6e775a9/41467_2024_50935_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/25b7cbe027b0/41467_2024_50935_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/609d22aa3c78/41467_2024_50935_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/3a22ff805ab1/41467_2024_50935_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/ffd97192141b/41467_2024_50935_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/0107d0bed111/41467_2024_50935_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/21c2/11310516/28d81ca3cbfb/41467_2024_50935_Fig7_HTML.jpg

相似文献

1
Achiral hard bananas assemble double-twist skyrmions and blue phases.非手性硬香蕉组装成双扭曲斯格明子和蓝相。
Nat Commun. 2024 Aug 8;15(1):6780. doi: 10.1038/s41467-024-50935-4.
2
Precursor skyrmion states near the ordering temperatures of chiral magnets.在手性磁体有序温度附近的前驱斯格明子态。
Phys Chem Chem Phys. 2023 Nov 1;25(42):28691-28702. doi: 10.1039/d3cp03034b.
3
Quasi-two-dimensional Skyrmion lattices in a chiral nematic liquid crystal.手性向列相液晶中的准二维斯格明子晶格。
Nat Commun. 2011;2:246. doi: 10.1038/ncomms1250.
4
Surface anchoring as a control parameter for shaping skyrmion or toron properties in thin layers of chiral nematic liquid crystals and noncentrosymmetric magnets.表面锚定作为手性向列型液晶和非中心对称磁体薄层中塑造斯格明子或托伦性质的控制参数。
Phys Rev E. 2021 Oct;104(4-1):044701. doi: 10.1103/PhysRevE.104.044701.
5
Self-assembly and electrostriction of arrays and chains of hopfion particles in chiral liquid crystals.手性液晶中霍普夫离子粒子阵列和链的自组装与电致伸缩
Nat Commun. 2015 Jan 21;6:6012. doi: 10.1038/ncomms7012.
6
Spontaneous organization and phase separation of skyrmions in chiral active matter.手性活性物质中斯格明子的自发组织与相分离
Soft Matter. 2022 Oct 5;18(38):7348-7359. doi: 10.1039/d2sm00819j.
7
Field-controlled dynamics of skyrmions and monopoles.斯格明子和磁单极子的场控动力学
Sci Adv. 2024 Jan 26;10(4):eadj9373. doi: 10.1126/sciadv.adj9373.
8
Current-induced skyrmion dynamics in constricted geometries.受限几何结构中的电流诱导斯格明子动力学。
Nat Nanotechnol. 2013 Oct;8(10):742-7. doi: 10.1038/nnano.2013.176. Epub 2013 Sep 8.
9
Optical generation of crystalline, quasicrystalline, and arbitrary arrays of torons in confined cholesteric liquid crystals for patterning of optical vortices in laser beams.在受限胆甾相液晶中通过光学方法生成用于激光束中光学涡旋图案化的晶态、准晶态和任意阵列的toron。
Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Aug;86(2 Pt 1):021703. doi: 10.1103/PhysRevE.86.021703. Epub 2012 Aug 27.
10
Thermal Hysteresis and Ordering Behavior of Magnetic Skyrmion Lattices.磁性斯格明子晶格的热滞现象与有序行为。
Nano Lett. 2022 Oct 12;22(19):7804-7810. doi: 10.1021/acs.nanolett.2c02275. Epub 2022 Sep 21.

引用本文的文献

1
Relationship between the Size of Bent-Shaped Molecules and Mesophase Formation: A Computational Study.弯曲形分子大小与中间相形成之间的关系:一项计算研究。
J Phys Chem B. 2025 Jul 17;129(28):7361-7371. doi: 10.1021/acs.jpcb.4c08662. Epub 2025 Jul 7.
2
Supramolecular Organization in Monolayers of Pyrene-Functionalized Asymmetric Twist-Bend Nematic Dimers: Comparison with a Three-Dimensional Crystal Structure.芘功能化不对称扭曲弯曲向列二聚体单层中的超分子组织:与三维晶体结构的比较。
Langmuir. 2025 Apr 15;41(14):9508-9519. doi: 10.1021/acs.langmuir.5c00551. Epub 2025 Apr 2.

本文引用的文献

1
Splay-bend nematic phases of bent colloidal silica rods induced by polydispersity.多分散性诱导的弯曲胶体二氧化硅棒的展曲向列相。
Nat Commun. 2022 Dec 1;13(1):7264. doi: 10.1038/s41467-022-34658-y.
2
Coupling between splay deformations and density modulations in splay-bend phases of bent colloidal rods.弯曲胶体棒的展曲-弯曲相中的展曲形变与密度调制之间的耦合
Phys Rev E. 2022 Feb;105(2):L022701. doi: 10.1103/PhysRevE.105.L022701.
3
Modulated phases of nematic liquid crystals induced by tetrahedral order.由四面体有序诱导的向列型液晶的调制相
Phys Rev E. 2022 Feb;105(2-1):024708. doi: 10.1103/PhysRevE.105.024708.
4
Hierarchical self-assembly of polydisperse colloidal bananas into a two-dimensional vortex phase.多分散胶体香蕉的分级自组装成二维涡旋相。
Proc Natl Acad Sci U S A. 2021 Aug 17;118(33). doi: 10.1073/pnas.2107241118.
5
A generalized density-modulated twist-splay-bend phase of banana-shaped particles.香蕉形粒子的广义密度调制扭曲-展曲-弯曲相。
Nat Commun. 2021 Apr 12;12(1):2157. doi: 10.1038/s41467-021-22413-8.
6
General liquid-crystal theory for anisotropically shaped molecules: Symmetry, orientational order parameters, and system free energy.各向异性形状分子的通用液晶理论:对称性、取向序参数和系统自由能。
Phys Rev E. 2020 Dec;102(6-1):062701. doi: 10.1103/PhysRevE.102.062701.
7
Origin and structure of liquid crystalline Blue Phase III.蓝相 III 的起源和结构。
Sci Rep. 2020 Sep 29;10(1):16016. doi: 10.1038/s41598-020-72086-4.
8
Shaping colloidal bananas to reveal biaxial, splay-bend nematic, and smectic phases.将胶体香蕉塑造成具有双轴、展曲-弯曲向列相和层状相。
Science. 2020 Aug 21;369(6506):950-955. doi: 10.1126/science.abb4536.
9
Geometry of Bend: Singular Lines and Defects in Twist-Bend Nematics.弯曲的几何形状:扭曲-弯曲向列相中的奇异线和缺陷
Phys Rev Lett. 2020 Jul 24;125(4):047801. doi: 10.1103/PhysRevLett.125.047801.
10
Biaxial, Twist-bend, and Splay-bend Nematic Phases of Banana-shaped Particles Revealed by Lifting the "Smectic Blanket".通过掀起“近晶相毯”揭示香蕉形粒子的双轴向、扭曲-弯曲和倾斜弯曲向列相
Phys Rev Lett. 2019 Aug 9;123(6):068001. doi: 10.1103/PhysRevLett.123.068001.