光氧化还原/铜双催化炔丙基衍生物的磷硫酰化反应用于可切换合成α-烷基、α-乙烯基和α-联烯基磷硫酯
Photoredox/Copper Dual-Catalyzed Phosphorothiolation of Propargylic Derivatives for the Switchable Synthesis of -Alkyl, -Vinyl and -Allenyl Phosphorothioates.
作者信息
Shi Shanshan, Chen Hu, Yang Shiwei, Dong Huaze, Zhu Jinmiao, Zheng Bin, Wang Xiaohong, Liang Zhaoyang, Ren Hongyu, Gao Yuzhen
机构信息
Department of Chemical and Pharmaceutical Engineering, Hefei Normal University, 230061, Hefei, Anhui, China.
State Key Laboratory of Structural Chemistry, Center for Excellence in Molecular Synthesis, Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China.
出版信息
Org Lett. 2024 Aug 23;26(33):7049-7054. doi: 10.1021/acs.orglett.4c02636. Epub 2024 Aug 9.
Herein, we report a photoredox/copper dual-catalyzed selective phosphorothiolation of propargylic derivatives from easily accessible [P(O)SH] compounds. This reaction provides a general, mild and versatile procedure to synthesize a variety of synthetically useful -alkyl, -vinyl and -allenyl phosphorothioates selectively from the same set of simple starting materials.
在此，我们报道了一种由易于获得的[P(O)SH]化合物进行的光氧化还原/铜双催化的炔丙基衍生物选择性硫代磷酸化反应。该反应提供了一种通用、温和且多功能的方法，可从同一组简单起始原料中选择性地合成各种具有合成用途的α-烷基、α-乙烯基和α-联烯基硫代磷酸酯。
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