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用于红外固态激光器的掺杂稀土氧化物碲酸盐玻璃的热学和光谱性质研究

Investigation of Thermal and Spectroscopic Properties of Tellurite-Based Glasses Doped with Rare-Earth Oxides for Infrared Solid-State Lasers.

作者信息

Boussetta Ahlem, Al-Syadi Aref M, Damak Kamel, Ersundu Ali Erçin, Çelikbilek Ersundu Miray, Ramadan Essam, Alshehri Ali M, Hussein Khalid I, Maalej Ramzi, Yousef El Sayed

机构信息

Laboratory of Systems Integration and Emerging Energies, National Engineering School of Sfax (ENIS), University of Sfax, Sfax 3018, Tunisia.

Department of Physics, Faculty of Science and Arts, Najran University, Najran 11001, Saudi Arabia.

出版信息

Materials (Basel). 2024 Jul 27;17(15):3717. doi: 10.3390/ma17153717.

DOI:10.3390/ma17153717
PMID:39124381
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11313676/
Abstract

The thermal and optical properties of 60TeO-20KTeO-10WO-10NbO (in mol%) glasses doped with HoO, ErO, and TmO were explored in the present work. The thermal stability, refractive index n, extinction coefficient k, absorption coefficient α, and optical band gap of the glasses were evaluated. The UV-Vis-NIR absorption spectra, the Judd-Ofelt intensity parameter, the spectroscopic quality factor, and the emission and absorption cross-sections were calculated to investigate the effects of Er and Tm, respectively, on the band spectroscopic properties of Ho ions. The results showed that the maximum emission cross-section was approximately 8×10-21 cm2, and the values of the full width at half maximum (FWHM), quality factor (σe×FWHM), and gain coefficient of Ho: I→I were also reported. The value of the FWHM×σe was 1200×10-28 cm3, which showed greater gain characteristics than earlier study results. For 2 μm mid-infrared solid-state lasers, the glasses that were examined might be a good host material.

摘要

在本工作中，对掺杂HoO、ErO和TmO的60TeO-20KTeO-10WO-10NbO（摩尔百分比）玻璃的热学和光学性质进行了研究。评估了玻璃的热稳定性、折射率n、消光系数k、吸收系数α和光学带隙。计算了紫外-可见-近红外吸收光谱、贾德-奥费尔特强度参数、光谱品质因数以及发射和吸收截面，以分别研究Er和Tm对Ho离子能带光谱性质的影响。结果表明，最大发射截面约为8×10⁻²¹ cm²，还报道了Ho：I→I的半高宽（FWHM）、品质因数（σe×FWHM）和增益系数的值。FWHM×σe的值为1200×10⁻²⁸ cm³，这表明其增益特性比早期研究结果更好。对于2μm中红外固态激光器，所研究的玻璃可能是一种良好的基质材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce49/11313676/3db00b517105/materials-17-03717-g012.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce49/11313676/ec632fa99fde/materials-17-03717-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce49/11313676/1038eee22435/materials-17-03717-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce49/11313676/e05477f064de/materials-17-03717-g009.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce49/11313676/3db00b517105/materials-17-03717-g012.jpg

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