da Silva Junior Cláudio José Galdino, de Medeiros Alexandre D'Lamare Maia, Cavalcanti Anantcha Karla Lafaiete de Holanda, de Amorim Julia Didier Pedrosa, Durval Italo José Batista, Cavalcanti Yasmim de Farias, Converti Attilio, Costa Andréa Fernanda de Santana, Sarubbo Leonie Asfora
Instituto Avançado de Tecnologia e Inovação (IATI), Rua Potyra, 31, Prado, Recife 50751-310, Brazil.
Rede Nordeste de Biotecnologia (RENORBIO), Universidade Federal Rural de Pernambuco, Rua Dom Manuel de Medeiros, s/n, Dois Irmãos, Recife 52171-900, Brazil.
Materials (Basel). 2024 Jul 27;17(15):3732. doi: 10.3390/ma17153732.
The high consumption of packaging has led to a massive production of waste, especially in the form of nonbiodegradable polymers that are difficult to recycle. Microbial cellulose is considered a biodegradable, low-cost, useful, ecologically correct polymer that may be joined with other biomaterials to obtain novel characteristics and can, therefore, be used as a raw material to produce packaging. Bagasse, a waste rich in plant cellulose, can be reprocessed and used to produce and reinforce other materials. Based on these concepts, the aim of the current research was to design sustainable packaging material composed of bacterial cellulose (BC) and sugarcane bagasse (SCB), employing an innovative shredding and reconstitution method able to avoid biomass waste. This method enabled creating a uniform structure with a 0.10-cm constant thickness, classified as having high grammage. The developed materials, particularly the 0.7 BC/0.3 SCB [70% (/) BC plus 30% (/) SCB] composite, had considerable tensile strength (up to 46.22 MPa), which was nearly thrice that of SCB alone (17.43 MPa). Additionally, the sorption index of the 0.7 BC/0.3 SCB composite (235.85 ± 31.29 s) was approximately 300-times higher than that of SCB (0.78 ± 0.09 s). The packaging material was also submitted to other analytical tests to determine its physical and chemical characteristics, which indicated that it has excellent flexibility and can be folded 100 times without tearing. Its surface was explored via scanning electron microscopy, which revealed the presence of fibers measuring 83.18 nm in diameter (BC). Greater adherence after the reconstitution process and even a uniform distribution of SCB fibers in the BC matrix were observed, resulting in greater tear resistance than SCB in its pure form. The results demonstrated that the composite formed by BC and SCB is promising as a raw material for sustainable packaging, due to its resistance and uniformity.
包装的高消耗量导致了大量废物的产生,尤其是难以回收的不可生物降解聚合物形式的废物。微生物纤维素被认为是一种可生物降解、低成本、有用且生态正确的聚合物,它可以与其他生物材料结合以获得新特性,因此可作为生产包装的原材料。甘蔗渣是一种富含植物纤维素的废料,可以进行再加工并用于生产和增强其他材料。基于这些概念,当前研究的目的是设计一种由细菌纤维素(BC)和甘蔗渣(SCB)组成的可持续包装材料,采用一种能够避免生物质浪费的创新切碎和重构方法。这种方法能够创建一种厚度恒定为0.10厘米的均匀结构,归类为具有高克重。所开发的材料,特别是0.7 BC/0.3 SCB [70%(/)BC加30%(/)SCB]复合材料,具有相当高的拉伸强度(高达46.22兆帕),几乎是单独的SCB(17.43兆帕)的三倍。此外,0.7 BC/0.3 SCB复合材料的吸附指数(235.85±31.29秒)比SCB(0.78±0.09秒)高出约300倍。该包装材料还进行了其他分析测试以确定其物理和化学特性,结果表明它具有出色的柔韧性,可以折叠100次而不撕裂。通过扫描电子显微镜对其表面进行了探索,结果显示存在直径为83.18纳米的纤维(BC)。观察到重构过程后有更强的附着力,甚至SCB纤维在BC基质中分布均匀,从而使其比纯形式的SCB具有更强的抗撕裂性。结果表明,由BC和SCB形成的复合材料因其抗性和均匀性,有望成为可持续包装的原材料。