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基于耐磨且可重复使用模板的具有良好机械强度的超疏水聚二甲基硅氧烷聚合物薄膜的简便制备方法。

Facile Preparation of Superhydrophobic PDMS Polymer Films with Good Mechanical Strength Based on a Wear-Resistant and Reusable Template.

作者信息

Chen Zhi, Lu Shuang, Wei Yumeng, Zhang Guojun, Han Fenglin

机构信息

State Key Laboratory of Precision Manufacturing for Extreme Service Performance, College of Mechanical and Electrical Engineering, Central South University, Changsha 410083, China.

Guangdong Provincial Key Laboratory of Manufacturing Equipment Digitization, Guangdong HUST Industrial Technology Research Institute, Dongguan 523808, China.

出版信息

Polymers (Basel). 2024 Jul 30;16(15):2165. doi: 10.3390/polym16152165.

Abstract

In this paper, a new method involving a wear-resistant and reusable template is proposed for the preparation of high-mechanical-strength superhydrophobic polymer film based on wire electrical discharge machining (WEDM). A solid-liquid-contact-angle simulation model was established to obtain surface-texture types and sizes that may achieve superhydrophobicity. The experimental results from template preparation show that there is good agreement between the simulation and experimental results for the contact angle. The maximum contact angle on the template can reach 155.3° given the appropriate triangular surface texture and WEDM rough machining. Besides, the prepared superhydrophobic template exhibits good wear resistance and reusability. PDMS superhydrophobic polymer films were prepared by the template method, and their properties were tested. The experimental results from the preparation of superhydrophobic polymer films show that the maximum contact angle of the polymer films can be up to 154.8° and that these films have good self-cleaning and anti-icing properties, wear resistance, bending resistance, and ductility.

摘要

本文提出了一种基于电火花线切割加工(WEDM)制备高机械强度超疏水聚合物薄膜的新方法,该方法涉及一种耐磨且可重复使用的模板。建立了固液接触角模拟模型,以获得可能实现超疏水性的表面纹理类型和尺寸。模板制备的实验结果表明,接触角的模拟结果与实验结果吻合良好。在适当的三角形表面纹理和电火花线切割粗加工条件下,模板上的最大接触角可达155.3°。此外,制备的超疏水模板具有良好的耐磨性和可重复使用性。采用模板法制备了聚二甲基硅氧烷(PDMS)超疏水聚合物薄膜,并对其性能进行了测试。超疏水聚合物薄膜制备的实验结果表明,聚合物薄膜的最大接触角可达154.8°,且这些薄膜具有良好的自清洁、抗结冰性能、耐磨性、抗弯曲性和延展性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ce3d/11315042/eca7e83f8e0e/polymers-16-02165-g001.jpg

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