Chen Nuo, Li Decai, Nie Shilin
Tsinghua University State Key Laboratory of Tribology, Beijing 100084, China.
ACS Omega. 2024 Jul 22;9(31):33522-33527. doi: 10.1021/acsomega.4c01060. eCollection 2024 Aug 6.
In this study, the mechanism by which combined surfactants affect the dispersion stability of magnetic nanofluids (MNFs) was improved. Two stable lubricating oil-based magnetic nanofluids with high viscosity and one with low viscosity were prepared by chemical coprecipitation. Erucic acid and octanoic acid were used as the combined surfactants to modify the FeO nanoparticles (MNPs). The size and morphology of the particles were observed using TEM. The rheological properties were tested with a rotational rheometer. The magnetization of the lubricating oil-based magnetic nanofluids was characterized by VSM. The results indicated that the prepared magnetic nanofluids had high viscosity, high magnetism, and good stability. This study provided ideas for the preparation of a high-viscosity magnetic nanofluid. By using combined surfactants, sufficient steric repulsion energy can be provided to counteract the attraction energy of sterically protected nanoparticles, thus achieving a balance of the dispersion stability of MNF.
在本研究中,联合表面活性剂影响磁性纳米流体(MNFs)分散稳定性的机制得到了改进。通过化学共沉淀法制备了两种高粘度的稳定润滑油基磁性纳米流体和一种低粘度的稳定润滑油基磁性纳米流体。芥酸和辛酸用作联合表面活性剂来修饰FeO纳米颗粒(MNPs)。使用透射电子显微镜观察颗粒的尺寸和形态。用旋转流变仪测试流变性能。用振动样品磁强计表征润滑油基磁性纳米流体的磁化强度。结果表明,所制备的磁性纳米流体具有高粘度、高磁性和良好的稳定性。本研究为高粘度磁性纳米流体的制备提供了思路。通过使用联合表面活性剂,可以提供足够的空间排斥能来抵消空间保护纳米颗粒的吸引能,从而实现MNF分散稳定性的平衡。