Zhang Hui, Du Xinyu, Liu Yongjiang, Lei Guorong, Yin Ping, Pang Siping
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
Beijing Institute of Technology Chongqing Innovation Center, Chongqing 401120, China.
ACS Omega. 2024 Jul 26;9(31):33557-33562. doi: 10.1021/acsomega.4c01261. eCollection 2024 Aug 6.
Azido, amino, and azo functionalities were introduced into tetrazine backbones to access multifunctional energetic materials. demonstrates effective initiation capability (MPC = 50 mg), whereas balances well between the energy and stability. Azo-functionalized has a high density of 1.908 g cm, with performance comparable to that of the benchmark material . This work underscores the scope of energetic functionalization and the outstanding comprehensive performance of polycyclic tetrazines.
将叠氮基、氨基和偶氮官能团引入四嗪主链以获得多功能含能材料。 表现出有效的起爆能力(最小起爆药量 = 50毫克),而 在能量和稳定性之间取得了良好的平衡。偶氮官能化的 具有1.908克/立方厘米的高密度,其性能与基准材料 相当。这项工作强调了含能官能化的范围以及多环四嗪出色的综合性能。