Curved Structure Regulated Single Metal Sites for Advanced Electrocatalytic Reactions.

Curved surface with defined local electronic structures and regulated surface microenvironments is significant for advanced catalytic engineering. Since single-atom catalysts are highly efficient and active, they have attracted much attention in recent years. The curvature carrier has a significant effect on the electronic structure regulation of single-atom sites, which effectively promote the catalytic efficiency. Here, the effect of the curvature structure with exposed metal atoms for catalysis is comprehensively summarized. First, the substrates with curvature features are reviewed. Second, the applications of single-atom catalysts containing curvature in a variety of different electrocatalytic reactions are discussed in depth. The impact of curvature effects in catalytic reactions is further analyzed. Finally, prospects and suggestions for their application and future development are presented. This review paves the way for the construction of high curvature-containing surface carriers, which is of great significance for single-atom catalysts development.