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一个甾醇数据库:74种油中150种甾醇的气相色谱/质谱数据及存在情况

A sterol database: GC/MS data and occurrence of 150 sterols in seventy-four oils.

作者信息

Schlag Sarah, Schäfer Sabrina, Sommer Katrin, Vetter Walter

机构信息

University of Hohenheim, Institute of Food Chemistry (170b), Garbenstraße 28, D-70599 Stuttgart, Germany.

University of Hohenheim, Institute of Food Chemistry (170b), Garbenstraße 28, D-70599 Stuttgart, Germany.

出版信息

Food Chem. 2024 Dec 1;460(Pt 3):140778. doi: 10.1016/j.foodchem.2024.140778. Epub 2024 Aug 6.

Abstract

Comprehensive data on the occurrence of sterols in plant oils is currently hardly available since only a few sterols are obtainable as standard compounds. Accordingly, many peaks are rarely labeled in gas chromatograms due to missing or outdated information. This lack of information hampers the progress in sterol research. For this reason, gas chromatography with mass spectrometry in selected ion monitoring mode (GC/MS-SIM) was used to create a database that summarizes the occurrence and semi-quantitative levels of 150 sterols with 27-32 carbon atoms and 0-4 double bonds in 66 different vegetable oils and eight other matrices. The highest number of sterols was detected in rice bran and tamanu oil (40 sterols), eggplant (39 sterols), moringa, chili seed, and amaranth oil (37 sterols). Several sterols were detected in >60 of the 74 matrices. This detailed information in the database will serve users working in food authentication and the biosynthesis of sterols.

摘要

目前几乎没有关于植物油中甾醇含量的全面数据,因为只有少数甾醇可作为标准化合物获得。因此,由于信息缺失或过时,气相色谱图中许多峰很少被标记。这种信息缺乏阻碍了甾醇研究的进展。因此,采用选择离子监测模式的气相色谱-质谱联用(GC/MS-SIM)来创建一个数据库,该数据库总结了66种不同植物油和其他8种基质中150种含27 - 32个碳原子和0 - 4个双键的甾醇的含量及半定量水平。在米糠油和山榄果油(40种甾醇)、茄子(39种甾醇)、辣木、辣椒籽和苋菜油(37种甾醇)中检测到的甾醇数量最多。在74种基质中的60多种中检测到了几种甾醇。数据库中的这些详细信息将为从事食品鉴定和甾醇生物合成工作的用户提供帮助。

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