手性诱导自旋选择性效应的化学视角。
A chemical perspective on the chiral induced spin selectivity effect.
作者信息
Bloom Brian P, Chen Zhongwei, Lu Haipeng, Waldeck David H
机构信息
Department of Chemistry, University of Pittsburgh, Pittsburgh 15260, USA.
Department of Chemistry, The Hong Kong University of Science and Technology, Kowloon, Hong Kong 999077, China.
出版信息
Natl Sci Rev. 2024 Jun 21;11(9):nwae212. doi: 10.1093/nsr/nwae212. eCollection 2024 Sep.
This review discusses opportunities in chemistry that are enabled by the chiral induced spin selectivity (CISS) effect. First, the review begins with a brief overview of the seminal studies on CISS. Next, we discuss different chiral material systems whose properties can be tailored through chemical means, with a special emphasis on hybrid organic-inorganic layered materials that exhibit some of the largest spin filtering properties to date. Then, we discuss the promise of CISS for chemical reactions and enantioseparation before concluding.
本综述讨论了由手性诱导自旋选择性（CISS）效应带来的化学领域的机遇。首先，综述开篇简要概述了关于CISS的开创性研究。接下来，我们讨论了不同的手性材料体系，其性质可通过化学方法进行调控，特别强调了有机-无机杂化层状材料，这类材料展现出了迄今为止一些最大的自旋过滤特性。然后，在总结之前，我们讨论了CISS在化学反应和对映体分离方面的前景。
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