Chu Mingi, Noh Eunjeong, Lee Kwang-Geun
Department of Food Science and Biotechnology, Dongguk University-Seoul, 32, Dongguk-ro, Ilsandong-gu, Goyang-si, Gyeonggi-do 10326 Republic of Korea.
Food Sci Biotechnol. 2024 Jan 17;33(10):2275-2287. doi: 10.1007/s10068-023-01494-9. eCollection 2024 Jul.
This study sought to analyze the oxidative products [acid value (AV), free fatty acids (FFA), conjugated dienoic acid (CDA), p-anisidine value (p-AV), antioxidant-prooxidant balance (APB) value] and toxic compounds [3-monochloropropane diol (3-MCPD), glycidyl ester (GE)] in edible oils after deep-frying. The deep-frying edible oils evaluated herein included soybean oil (S), palm oil (P), canola oil (C), grape seed oil (G), and a 1:1 blend (SC, SG, PC, PG, and CG). As frying time increased, the level of AV in PC, total FFA contents in CG, and p-AV in CG significantly increased up to 200%, 45.5%, and 410.5%, respectively (p < 0.05). The levels of 3-MCPD, and GE were 0.81-6.28 µg/mL and 0.14-2.84 µg/mL, respectively. The levels of 3-MCPD, GE, CDA, and APB changed significantly as frying time increased. Analysis of the correlation between oxidation products and toxic compounds indicated that the contents of 3-MCPD and palmitic acid were positively correlated.
The online version contains supplementary material available at 10.1007/s10068-023-01494-9.
本研究旨在分析深度油炸后食用油中的氧化产物[酸值(AV)、游离脂肪酸(FFA)、共轭二烯酸(CDA)、对茴香胺值(p-AV)、抗氧化剂-促氧化剂平衡(APB)值]和有毒化合物[3-氯-1,2-丙二醇(3-MCPD)、缩水甘油酯(GE)]。本文评估的深度油炸食用油包括大豆油(S)、棕榈油(P)、菜籽油(C)、葡萄籽油(G)以及1:1的混合油(SC、SG、PC、PG和CG)。随着油炸时间的增加,PC中的AV水平、CG中的总FFA含量以及CG中的p-AV分别显著增加了200%、45.5%和410.5%(p < 0.05)。3-MCPD和GE的水平分别为0.81 - 6.28μg/mL和0.14 - 2.84μg/mL。随着油炸时间的增加,3-MCPD、GE、CDA和APB的水平发生了显著变化。氧化产物与有毒化合物之间的相关性分析表明,3-MCPD的含量与棕榈酸呈正相关。
在线版本包含可在10.1007/s10068-023-01494-9获取的补充材料。