双（二亚胺基）硼二氟配合物：双（硼正离子）阳离子的有效合成子。
Bis(diiminate)-based boron difluoro complexes: effective synthon for bis(borenium) cations.
作者信息
Parveen Darakshan, Yadav Rahul Kumar, Mondal Bijan, Dallon Marie, Sarazin Yann, Roy Dipak Kumar
机构信息
Department of Chemistry, Indian Institute of Technology Indore, Madhya Pradesh, 453552, India.
Institute of Inorganic Chemistry, Universität Regensburg, Universität Strasse 31, 93040 Regensburg, Germany.
出版信息
Dalton Trans. 2024 Aug 27;53(34):14139-14143. doi: 10.1039/d4dt02050b.
A series of boron difluoro bis(diiminate) complexes have been prepared and used to obtain triflate substituted fluoroborane complexes. The corresponding well-defined bis(borenium) cations were subsequently synthesized and structurally authenticated. We are also presenting the first experimental and theoretical study of bis(borenium) cations that are derivative of cationic borinic acid.
已经制备了一系列二氟硼双（二亚胺）配合物，并用于获得三氟甲磺酸酯取代的氟硼烷配合物。随后合成了相应的结构明确的双（硼鎓）阳离子并进行了结构鉴定。我们还展示了对阳离子硼酸衍生物双（硼鎓）阳离子的首次实验和理论研究。
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