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聚砜膜浸渍黄麻-铜纳米复合材料作为高效染料去除材料

PSf Membrane-Impregnated Jute-Copper Nanocomposite as Highly Efficient Dye Removal Material.

作者信息

Prajapati Harsh, Dave Hemen, Busupalli Balanagulu

机构信息

Department of Chemistry, Pandit Deendayal Energy University (PDEU), Gandhinagar, Gujarat 382426, India.

National Forensic Sciences University, Gandhinagar, Gujarat 382007, India.

出版信息

ACS Omega. 2024 Aug 2;9(32):34292-34302. doi: 10.1021/acsomega.3c09966. eCollection 2024 Aug 13.

Abstract

Water pollution, driven by the discharge of dyes from industrial processes, poses a significant environmental and health hazard worldwide. Methylene blue, a common dye, constitutes particular concern due to its persistence and toxicity. Conventional wastewater treatment methods often struggle to effectively remove such contaminants. In this study, we introduce a novel approach utilizing a polysulfone-based composite membrane incorporating pretreated jute fibers and copper nanoparticles for the removal of methylene blue from aqueous solutions. The pretreated jute fibers undergo alkali and hydrogen peroxide treatments to enhance their adsorption capabilities, while copper nanoparticles are incorporated into the membrane to bolster its antimicrobial properties. Through comprehensive characterization techniques, including Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), dynamic light scattering (DLS), and scanning electron microscopy (SEM), we confirm the structural and chemical properties of the composite membranes. Batch adsorption studies reveal the superior performance of the composite membrane compared with individual components. Specifically, at lower methylene blue concentrations (∼20 ppm), the composite membrane demonstrates a remarkable percent removal value of about 97%, while at higher concentrations (∼100 ppm), the percent removal remains substantial at 85%. Additionally, desorption studies elucidate the retention capacity of the adsorbed dye, indicating the feasibility of the composite membrane for practical applications in wastewater treatment. These findings underscore the potential of nanocomposite-fiber membranes as sustainable and cost-effective solutions for mitigating water pollution. By harnessing advancements in nanotechnology and materials science, the presented innovative composite membranes could offer promising avenues for addressing water pollution challenges and promoting environmental sustainability.

摘要

工业生产过程中染料排放导致的水污染在全球范围内构成了重大的环境和健康危害。亚甲基蓝作为一种常见染料,因其持久性和毒性而备受关注。传统的废水处理方法往往难以有效去除此类污染物。在本研究中,我们引入了一种新颖的方法,利用一种基于聚砜的复合膜,该复合膜包含经过预处理的黄麻纤维和铜纳米颗粒,用于从水溶液中去除亚甲基蓝。经过预处理的黄麻纤维经过碱处理和过氧化氢处理以增强其吸附能力,同时将铜纳米颗粒掺入膜中以增强其抗菌性能。通过包括傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)、动态光散射(DLS)和扫描电子显微镜(SEM)在内的综合表征技术,我们确定了复合膜的结构和化学性质。批量吸附研究表明,复合膜的性能优于单个组件。具体而言,在较低的亚甲基蓝浓度(约20 ppm)下,复合膜的去除率高达约97%,而在较高浓度(约100 ppm)下,去除率仍高达85%。此外,解吸研究阐明了吸附染料的保留能力,表明复合膜在废水处理实际应用中的可行性。这些发现强调了纳米复合纤维膜作为减轻水污染的可持续且经济高效解决方案的潜力。通过利用纳米技术和材料科学的进步,所展示的创新复合膜可为应对水污染挑战和促进环境可持续性提供有前景的途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c0a3/11325434/c8152424eab8/ao3c09966_0001.jpg

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