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在电聚合聚苯胺上生长钼酸钙作为用于增强析氧的混合电催化剂。

growth of CaMoO on electropolymerized PANI as a hybrid electrocatalyst for enhanced oxygen evolution.

作者信息

Garg Nitika, Ganguli Ashok K

机构信息

Department of Chemistry, Indian Institute of Technology Delhi Hauz Khas New Delhi-110016 India

Department of Chemical Sciences, Indian Institute of Science Education and Research Berhampur Ganjam Odisha-760003 India.

出版信息

RSC Adv. 2024 Aug 20;14(36):26292-26301. doi: 10.1039/d4ra03196b. eCollection 2024 Aug 16.

DOI:10.1039/d4ra03196b
PMID:39165787
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11334154/
Abstract

Electrochemical water splitting stands as a promising avenue for sustainable hydrogen production, with the oxygen evolution reaction (OER) playing a pivotal role. Efficient and durable electrocatalysts are crucial for expediting the sluggish kinetics of OER. In this work, we investigate the synthesis and performance of a novel CaMoO/polyaniline (CaMoO/PANI) composite catalyst for OER. growth of CaMoO has been done after the electropolymerization of polyaniline on nickel foam (NF), offering advantages such as improved structural integrity, increased surface area, and enhanced electroconductivity. Electrochemical characterization reveals that CaMoO/PANI exhibits superior catalytic activity, with an overpotential of 233 mV at 10 mA cm, outperforming pristine CaMoO, PANI, and certain current similar non-noble-metal electrocatalysts. Electrochemical studies reveal that the exceptional activity can be attributed to reduced charge transfer resistance, underscoring the catalyst's enhanced efficiency. Furthermore, multistep chronopotentiometry confirms excellent robustness of the catalyst electrode as well as its excellent mass transportation. This work highlights the potential of inorganic oxide/conductive polymer composites as efficient catalysts for OER, offering insights for future developments in sustainable energy technologies.

摘要

电化学水分解是可持续制氢的一条有前景的途径,其中析氧反应(OER)起着关键作用。高效且耐用的电催化剂对于加速迟缓的OER动力学至关重要。在这项工作中,我们研究了一种用于OER的新型钼酸钙/聚苯胺(CaMoO/PANI)复合催化剂的合成及性能。聚苯胺在泡沫镍(NF)上进行电聚合后再生长钼酸钙,具有诸如改善结构完整性、增加表面积和提高电导率等优点。电化学表征表明,CaMoO/PANI表现出优异的催化活性,在10 mA cm时过电位为233 mV,优于原始的CaMoO、PANI以及某些目前类似的非贵金属电催化剂。电化学研究表明,这种卓越的活性可归因于电荷转移电阻的降低,突出了该催化剂提高的效率。此外,多步计时电位法证实了催化剂电极具有出色的稳定性以及优异的传质性能。这项工作突出了无机氧化物/导电聚合物复合材料作为OER高效催化剂的潜力,为可持续能源技术的未来发展提供了见解。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f26/11334154/401a2df131d4/d4ra03196b-f10.jpg
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本文引用的文献

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Electrochemical and chemical cycle for high-efficiency decoupled water splitting in a near-neutral electrolyte.近中性电解质中高效解耦水分解的电化学和化学循环
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Cooperative Fe sites on transition metal (oxy)hydroxides drive high oxygen evolution activity in base.
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