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碳量子点在电化学储能器件中的应用。

Applications of carbon quantum dots in electrochemical energy storage devices.

作者信息

Arora Grishika, Sabran Nuur Syahidah, Ng Chai Yan, Low Foo Wah, Jun H K

机构信息

Department of Mechanical and Materials Engineering, Lee Kong Chian Faculty of Engineering and Science, Universiti Tunku Abdul Rahman, Sungai Long Campus, Bandar Sungai Long, 43000, Kajang, Malaysia.

Centre for Advanced and Sustainable Materials Research, Universiti Tunku Abdul Rahman, Sungai Long Campus, Bandar Sungai Long, 43000, Kajang, Malaysia.

出版信息

Heliyon. 2024 Aug 2;10(15):e35543. doi: 10.1016/j.heliyon.2024.e35543. eCollection 2024 Aug 15.

Abstract

Supercapacitors (SCs), including electric double-layer capacitors (EDLCs), pseudocapacitors, and hybrid capacitors, are esteemed for their high power density and attractive features such as robust safety, fast charging, low maintenance, and prolonged cycling lifespan, sparking significant interest. Carbon quantum dots (CQDs) are fluorescent nanomaterials with small size, broad excitation spectrum, stable fluorescence, and adjustable emission wavelengths. They are widely used in optoelectronics, medical diagnostics, and energy storage due to their biocompatibility, low toxicity, rich surface functional groups, abundant electron-hole pairs, large specific surface area, and tunable heteroatom doping. In this short review, we briefly discussed the advantages and disadvantages of bottom-up and top-down of CQD synthesis methods. The arc-discharge technique, laser ablation technique, plasma treatment, ultrasound synthesis technique, electrochemical technique, chemical exfoliation, and combustion are among the initial top-down approaches. The subsequent section delineates waste-derived and bottom-up methods, encompassing microwave synthesis, hydrothermal synthesis, thermal pyrolysis, and the metal-organic framework template-assisted technique. In addition, this short review focuses on the operational mechanism of supercapacitors, their properties, and the utilization of CQDs in supercapacitors.

摘要

超级电容器(SCs),包括双电层电容器(EDLCs)、赝电容器和混合电容器,因其高功率密度以及诸如安全可靠、充电速度快、维护成本低和循环寿命长等吸引人的特性而备受推崇,引发了人们极大的兴趣。碳量子点(CQDs)是一种荧光纳米材料,具有尺寸小、激发光谱宽、荧光稳定以及发射波长可调节等特点。由于其生物相容性、低毒性、丰富的表面官能团、大量的电子 - 空穴对、大的比表面积以及可调节的杂原子掺杂,它们被广泛应用于光电子学、医学诊断和能量存储领域。在这篇简短的综述中,我们简要讨论了碳量子点合成方法中自下而上和自上而下方法的优缺点。电弧放电技术、激光烧蚀技术、等离子体处理、超声合成技术、电化学技术、化学剥离和燃烧属于最初的自上而下的方法。随后的部分描述了废物衍生和自下而上的方法,包括微波合成、水热合成、热解以及金属有机框架模板辅助技术。此外,这篇简短的综述聚焦于超级电容器的工作机制、其特性以及碳量子点在超级电容器中的应用。

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