Liu De-Xin, Meng Fan-Lei, Duan Hai-Jing, Li Yi-Meng, Ma Jian-Hua
College of Geography and Environmental Science, Henan University, Kaifeng 475004, China.
Key Laboratory of Geospatial Technology for the Middle and Lower Yellow River Regions, Ministry of Education, Henan University, Kaifeng 475004, China.
Huan Jing Ke Xue. 2024 Aug 8;45(8):4812-4824. doi: 10.13227/j.hjkx.202308126.
The contents of eight heavy metals (Cr, Ni, Cu, Zn, Cd, Pb, As, and Hg) were determined based on the surface soil samples of sewage irrigation and industrial complex in Kaifeng City. The absolute factor analysis-multiple linear regression (APCS-MLR) model and positive matrix factorization (PMF) model were used to analyze the sources and contribution rates of heavy metals in soil combined with correlation analysis and systematic cluster analysis. The results showed that: ① The average values of (Cr), (Ni), (Cu), (Zn), (Cd), (Pb), (As), and (Hg) in the study area were 52.19, 25.00, 42.03, 323.53, 1.79, 53.45, 9.43, and 0.20 mg·kg, respectively, and Cr, Ni, and As are lower than the background values of tidal soil. Cu, Zn, Cd, Pb, and Hg are higher than the background values of the tidal soil. ② There were four sources of the eight heavy metals: natural sources, agricultural sewage irrigation sources, industrial atmospheric sedimentation sources, and transportation sources. Cr and Ni were mainly from natural sources; Cu, Zn, Cd, and Pb were mainly from agricultural sewage irrigation and transportation sources; As was mainly from natural sources and agricultural sewage irrigation; and Hg was mainly from industrial atmospheric sedimentation. ③ The APCS-MLR and PMF source analysis results indicated that industrial and agricultural activities were the main sources of heavy metals in the soil of the study area. The average contribution rates of APCS-MLR in the nine sampling areas of the research area were 76.01% (natural sources and agricultural sewage irrigation sources), 22.71% (industrial atmospheric sedimentation sources and transportation sources), and 1.28% (unknown sources). The average contribution rates of PMF were 59.66% (natural sources and agricultural sewage irrigation sources) and 40.34% (industrial atmospheric sedimentation sources and transportation sources). The source analysis results of the LZ, XZ, NLT, PT, YLZ, and BC models were basically consistent, and WL was better in the APCS-MLR model, whereas SG and QT were better in the PMF model. The research results can provide a scientific basis for the prevention and control of soil heavy metal pollution and environmental remediation.
基于开封市污水灌溉区和工业集聚区的表层土壤样本,测定了8种重金属(铬、镍、铜、锌、镉、铅、砷和汞)的含量。结合相关性分析和系统聚类分析,采用绝对主成分分析-多元线性回归(APCS-MLR)模型和正定矩阵因子分解(PMF)模型分析土壤中重金属的来源及贡献率。结果表明:①研究区土壤中铬(Cr)、镍(Ni)、铜(Cu)、锌(Zn)、镉(Cd)、铅(Pb)、砷(As)和汞(Hg)的平均值分别为52.19、25.00、42.03、323.53、1.79、53.45、9.43和0.20mg·kg,其中Cr、Ni和As低于潮土背景值,Cu、Zn、Cd、Pb和Hg高于潮土背景值。②8种重金属有4个来源:自然源、农业污水灌溉源、工业大气沉降源和交通源。Cr和Ni主要来自自然源;Cu、Zn、Cd和Pb主要来自农业污水灌溉和交通源;As主要来自自然源和农业污水灌溉;Hg主要来自工业大气沉降。③APCS-MLR和PMF源解析结果表明,工农业活动是研究区土壤重金属的主要来源。研究区9个采样点APCS-MLR的平均贡献率分别为76.01%(自然源和农业污水灌溉源)、22.71%(工业大气沉降源和交通源)、1.28%(未知源)。PMF的平均贡献率分别为59.66%(自然源和农业污水灌溉源)、40.34%(工业大气沉降源和交通源)。LZ、XZ、NLT、PT、YLZ和BC模型的源解析结果基本一致,APCS-MLR模型中WL点位效果较好,PMF模型中SG和QT点位效果较好。研究结果可为土壤重金属污染防治和环境修复提供科学依据。