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通过焊接工程制备的全纤维素复合纱线。

All-cellulose composite yarn via welding engineering.

作者信息

Dong Zheng, Luo Yinqing, Zhao Lunyu, Wang Bijia, Mao Zhiping, Feng Xueling, Sui Xiaofeng

机构信息

Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China; Shanghai Belt and Road Joint Laboratory of Textile Intelligent Manufacturing, Donghua University, Shanghai 201620, China.

Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620, China; Shanghai Belt and Road Joint Laboratory of Textile Intelligent Manufacturing, Donghua University, Shanghai 201620, China; National Innovation Center of Advanced Dyeing & Finishing Technology, Shandong Zhongkang Guochuang Research Institute of Advanced Dyeing & Finishing Technology Co. Ltd., Tai'an, Shandong 271000, China.

出版信息

Carbohydr Polym. 2024 Nov 1;343:122462. doi: 10.1016/j.carbpol.2024.122462. Epub 2024 Jul 4.

Abstract

Due to the wide range of available raw materials and excellent biocompatibility, all-cellulose composites (ACCs) have received significant attention as a kind of renewable and biodegradable candidate to replace petroleum-based synthetic polymers. However, most current research of ACCs is limited to film and bulk materials. Herein, we present a simple, efficient, and scalable welding method for obtaining green, self-reinforced, high performance all-cellulose composite yarns by partially dissolving and regenerating cellulose yarns with phosphoric acid. The in-situ core-shell structure of the welded yarn results in improved strength (134.6 MPa), friction resistance (8000 cycles), moisture regain (11.89 %), and dyeing properties. Moreover, the regeneration and drying procedure can be optimized to further enhance the strength (190.5 MPa) of the welded yarn. This straightforward welding approach provides a promising and convenient route for manufacturing high-performance bio-based yarn.

摘要

由于可用原材料种类繁多且具有出色的生物相容性,全纤维素复合材料(ACC)作为一种可再生且可生物降解的材料,有望替代石油基合成聚合物,因此受到了广泛关注。然而,目前大多数关于ACC的研究仅限于薄膜和块状材料。在此,我们提出了一种简单、高效且可扩展的焊接方法,通过用磷酸部分溶解和再生纤维素纱线来制备绿色、自增强、高性能的全纤维素复合纱线。焊接纱线的原位核壳结构使其强度(134.6兆帕)、摩擦阻力(8000次循环)、回潮率(11.89%)和染色性能得到改善。此外,再生和干燥过程可以优化,以进一步提高焊接纱线的强度(190.5兆帕)。这种直接的焊接方法为制造高性能生物基纱线提供了一条有前景且便捷的途径。

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