可见光促进的-(1-炔基)苯甲酸酯的硒化/环化反应合成硒取代异香豆素
Visible-light-promoted selenylation/cyclization of -(1-alkynyl) benzoates to access seleno-substituted isocoumarins.
作者信息
Ren Mei-Lin, Gong Xi-Rui, Chen Yan-Yan, Xu Yan-Li
机构信息
Guangxi Key Laboratory of Drug Discovery and Optimization, Guangxi Engineering Research Center for Pharmaceutical Molecular Screening and Druggability Evaluation, Key Laboratory of Medical Biotechnology and Translational Medicine, School of Pharmacy, Guilin Medical University, Guilin 541199, Guangxi, China..
出版信息
Org Biomol Chem. 2024 Sep 18;22(36):7327-7331. doi: 10.1039/d4ob01010h.
A simple and efficient method to access 4-selenyl-isocoumarin derivatives through visible-light-promoted selenylation/cyclization of -(1-alkynyl) benzoates has been developed. This transformation is performed under mild conditions and has the advantages of functional group tolerance and broad substrate scope.
通过可见光促进的-(1-炔基)苯甲酸酯的硒化/环化反应来制备4-硒基异香豆素衍生物，已开发出一种简单有效的方法。该转化反应在温和条件下进行，具有官能团耐受性好和底物范围广的优点。
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