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一种用于捕获二氧化碳的环境友好型低共熔溶剂。

An environmentally friendly deep eutectic solvent for CO capture.

作者信息

Manafpour Ali Asghar, Feyzi Farzaneh, Rezaee Mehran

机构信息

Thermodynamic Research Laboratory, School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, 16846-13114, Iran.

出版信息

Sci Rep. 2024 Aug 26;14(1):19744. doi: 10.1038/s41598-024-70761-4.

DOI:10.1038/s41598-024-70761-4
PMID:39187626
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11347629/
Abstract

A leading cause of global warming is the increase of carbon dioxide (CO) emissions due to anthropogenic activities which prompts an urgent need for substantial reduction. Recently, CO absorption in deep eutectic solvents (DESs) has attracted scientific attention, because of their adaptability compared to traditional ionic liquids and aqueous amine solutions. This study employs the heating method to synthesize DESs using tetrapropylammonium bromide (TPAB) and formic acid (Fa) with molar ratios of TPAB-Fa (1:1) and TPAB-Fa (1:2). Absorption experiments by static method quantified CO solubility in the DESs under varied pressures and temperatures. TPAB-Fa (1:2) at 25.0 °C was the most efficient with the CO solubility of 0.218. Thermodynamic modeling was performed by employing the nonrandom two liquids activity coefficient model and the Peng-Robinson equation of state for the liquid and gas phases, respectively. The Henry's law constant was determined from experimental data. CO physical absorption was confirmed via nuclear magnetic resonance (NMR) and Fourier-transform infrared (FT-IR) analyses. TPAB-Fa (1:2), as the superior DES, exhibited regeneration efficiency of 99% after five absorption/desorption cycles.

摘要

全球变暖的一个主要原因是人为活动导致的二氧化碳（CO）排放量增加，这促使人们迫切需要大幅减排。最近，深共熔溶剂（DESs）对CO的吸收引起了科学界的关注，因为与传统离子液体和胺水溶液相比，它们具有更好的适应性。本研究采用加热法，以溴化四丙基铵（TPAB）和甲酸（Fa）为原料，摩尔比为TPAB-Fa（1:1）和TPAB-Fa（1:2）合成DESs。通过静态法进行吸收实验，量化了不同压力和温度下CO在DESs中的溶解度。在25.0°C时，TPAB-Fa（1:2）的效率最高，CO溶解度为0.218。分别采用非随机双液体活度系数模型和彭-罗宾逊状态方程对液相和气相进行热力学建模。根据实验数据确定亨利定律常数。通过核磁共振（NMR）和傅里叶变换红外（FT-IR）分析证实了CO的物理吸收。TPAB-Fa（1:2）作为性能优异的DES，在五个吸收/解吸循环后表现出99%的再生效率。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/b22992b09c67/41598_2024_70761_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/6e620bfe50a4/41598_2024_70761_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/b7fd4710043e/41598_2024_70761_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/2f1eda87e312/41598_2024_70761_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/1693141b4b14/41598_2024_70761_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/ddf6859c1cb9/41598_2024_70761_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/d3579bfc6f41/41598_2024_70761_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/139e4092e048/41598_2024_70761_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/b22992b09c67/41598_2024_70761_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/6e620bfe50a4/41598_2024_70761_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/b7fd4710043e/41598_2024_70761_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/2f1eda87e312/41598_2024_70761_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/1693141b4b14/41598_2024_70761_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/ddf6859c1cb9/41598_2024_70761_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/d3579bfc6f41/41598_2024_70761_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/139e4092e048/41598_2024_70761_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8944/11347629/b22992b09c67/41598_2024_70761_Fig8_HTML.jpg

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Sci Rep. 2024 Jan 10;14(1):954. doi: 10.1038/s41598-024-51586-7.
2
Experimental investigation of novel ternary amine-based deep eutectic solvents for CO2 capture.新型三元胺基深共晶溶剂用于 CO2 捕获的实验研究。
PLoS One. 2023 Jun 23;18(6):e0286960. doi: 10.1371/journal.pone.0286960. eCollection 2023.
3
Advances of Ionic Liquids and Deep Eutectic Solvents in Green Processes of Biomass-Derived 5-Hydroxymethylfurfural.
离子液体和深共晶溶剂在生物质衍生 5-羟甲基糠醛绿色过程中的进展。
ChemSusChem. 2022 Jul 7;15(13):e202102635. doi: 10.1002/cssc.202102635. Epub 2022 Feb 10.
4
Industrial Applications of Ionic Liquids.离子液体的工业应用。
Molecules. 2020 Nov 9;25(21):5207. doi: 10.3390/molecules25215207.
5
The Importance of Ionic Liquids in the Modification of Starch and Processing of Starch-Based Materials.离子液体在淀粉改性及淀粉基材料加工中的重要性。
Materials (Basel). 2020 Oct 9;13(20):4479. doi: 10.3390/ma13204479.
6
Preparation of Quaternary Ammonium Salt-Modified Chitosan Microspheres and Their Application in Dyeing Wastewater Treatment.季铵盐改性壳聚糖微球的制备及其在印染废水处理中的应用
ACS Omega. 2020 Sep 21;5(38):24700-24707. doi: 10.1021/acsomega.0c03274. eCollection 2020 Sep 29.
7
Key Applications and Potential Limitations of Ionic Liquid Membranes in the Gas Separation Process of CO, CH, N, H or Mixtures of These Gases from Various Gas Streams.离子液体膜在 CO、CH、N、H 或这些气体混合物从各种气流中的气体分离过程中的主要应用和潜在限制。
Molecules. 2020 Sep 18;25(18):4274. doi: 10.3390/molecules25184274.
8
Hydrophobic Functional Deep Eutectic Solvents Used for Efficient and Reversible Capture of CO.用于高效可逆捕获一氧化碳的疏水性功能化低共熔溶剂
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9
Carbon Dioxide Solubilities in Decanoic Acid-Based Hydrophobic Deep Eutectic Solvents.二氧化碳在基于癸酸的疏水性低共熔溶剂中的溶解度
J Chem Eng Data. 2018 Apr 12;63(4):913-919. doi: 10.1021/acs.jced.7b00534. Epub 2018 Mar 19.
10
In-situ capture and conversion of atmospheric CO into nano-CaCO using a novel pathway based on deep eutectic choline chloride-calcium chloride.利用基于深共晶氯化胆碱-氯化钙的新途径原位捕获和转化大气 CO 为纳米 CaCO。
J Environ Manage. 2018 Jan 15;206:516-522. doi: 10.1016/j.jenvman.2017.11.005. Epub 2017 Nov 8.