Fabrication and Characterization of Graphene-Mesoporous Carbon-Nickel-Poly(Vinyl Alcohol)-Coated Mandrel-Coiled TCP Artificial Muscle.

This study investigates the performance enhancement of mandrel-coiled twisted and coiled polymer fibers with a nichrome heater (TCP) by coating with a solution of graphene-mesoporous carbon-nickel-polyvinyl alcohol. The coating process involved a one-pot synthesis utilizing graphene powder, Ni nanoparticles, mesoporous carbon, and PVA as a binding agent. The coating was performed by manually shaking the TCP and the subsequent annealing process, which results in improved thermal conductivity and actuation behavior of the TCP. Experimental results on a 60 mm long actuator demonstrated significant enhancements in actuation displacement and actuation strain (20% to 42%) under various loads with an input current of 0.27 A/power 2.16 W. The blocked stress is ~10 MPa under this 2.16 W power input and the maximum strain is 48% at optimum load of 1.4 MPa. The observed actuation strain correlated directly with the input power. The coated TCP exhibited better thermal contacts, facilitating enhanced heat transfer, and reducing power consumption by 6% to 9% compared to non-coated actuators. It was found that the nanomaterial coating helps the TCP actuator to be reliable for more than 75,000 actuation cycles at 0.1 Hz in air due to improved thermal conductivity. These findings highlight the potential for further research to optimize electrothermally operated TCP actuators and unlock advancements in this field.