Cantele Carolina, Potenziani Giulia, Bonciolini Ambra, Bertolino Marta, Cardenia Vladimiro
Department of Agricultural, Forest and Food Sciences (DISAFA), University of Turin, 10095 Grugliasco, TO, Italy.
AgriForFood Chromatography and Mass Spectrometry Open Access Laboratory, University of Turin, 10095 Grugliasco, TO, Italy.
Antioxidants (Basel). 2024 Jul 30;13(8):930. doi: 10.3390/antiox13080930.
Due to their antioxidant activity, alkylresorcinols (ARs) extracted from by-products could represent promising natural and innovative antioxidants for the food industry. This study tested the ability of ARs isolated from wheat bran to increase the shelf-life of minced-meat models stored at 4 °C for 9 days. Fifteen alk(en)ylresorcinols (C17-C25) were recognized by GC/MS, showing good radical-scavenging (200.70 ± 1.33 μmolTE/g extract) and metal-chelating (1.38 ± 0.30 mgEDTAE/g extract) activities. Two ARs concentrations (0.01% and 0.02%) were compared to sodium ascorbate (0.01% and 0.10%) on color (CIELAB values , , , chroma, and hue) and oxidative stability (lipid hydroperoxides, thiobarbituric acid reactive substances (TBARS), and volatile organic compounds (VOCs)) of minced-beef samples. ARs-treated samples were oxidatively more stable than those formulated with sodium ascorbate and the negative control, with significantly lower contents of hydroperoxides and VOCs (hexanal, 1-hexanol, and 1-octen-3-ol) throughout the experiment ( < 0.001). However, no effect on color stability was observed ( > 0.05). Since 0.01% of ARs was equally or more effective than 0.10% sodium ascorbate, those results carry important implications for the food industry, which could reduce antioxidant amounts by ten times and replace synthetic antioxidants with natural ones.
由于其抗氧化活性,从副产品中提取的烷基间苯二酚(ARs)可能成为食品工业中颇具前景的天然创新型抗氧化剂。本研究测试了从麦麸中分离出的ARs延长在4℃下储存9天的碎肉模型保质期的能力。通过气相色谱/质谱法鉴定出15种烷(烯)基间苯二酚(C17 - C25),其具有良好的自由基清除能力(200.70±1.33μmol TE/g提取物)和金属螯合能力(1.38±0.30 mg EDTAE/g提取物)。将两种ARs浓度(0.01%和0.02%)与抗坏血酸钠(0.01%和0.10%)在碎牛肉样品的颜色(CIELAB值、、、色度和色调)和氧化稳定性(脂质氢过氧化物、硫代巴比妥酸反应性物质(TBARS)和挥发性有机化合物(VOCs))方面进行比较。经ARs处理的样品在氧化方面比用抗坏血酸钠和阴性对照配制的样品更稳定,在整个实验过程中,氢过氧化物和VOCs(己醛、1 - 己醇和1 - 辛烯 - 3 - 醇)的含量显著更低(<0.001)。然而,未观察到对颜色稳定性的影响(>0.05)。由于0.01%的ARs与0.10%的抗坏血酸钠效果相同或更优,这些结果对食品工业具有重要意义,食品工业可将抗氧化剂用量减少十倍,并用天然抗氧化剂替代合成抗氧化剂。