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日季卡林斯基矿床(哈萨克斯坦)蛇纹岩的热酸行为

Thermoacid Behavior of Serpentinite of the Zhitikarinsky Deposit (Kazakhstan).

作者信息

Auyeshov Abdrazak, Arynov Kazhymuhan, Yeskibayeva Chaizada, Alzhanov Kurmanbek, Raiymbekov Yerkebulan

机构信息

Scientific Research Laboratory "Applied Chemistry", M. Auezov South Kazakhstan University, Shymkent 160012, Kazakhstan.

"Institute of Innovative Research and Technology" LLP, Almaty 050010, Kazakhstan.

出版信息

Molecules. 2024 Aug 22;29(16):3965. doi: 10.3390/molecules29163965.

Abstract

Thermoacid behavior of serpentinite from the Zhitikarinsky field (g. Zhitikara, Kazakhstan). The character of dissolution of heat-treated serpentinite in a narrow temperature range of 600-750 °C is investigated, where the crystal lattice of the structural structure of chrysotile in sulfuric acid is destroyed. The X-ray and chemical analysis of the products of dissolution of heat-treated serpentinite at 600 °C, 725 °C and 750 °C in sulfuric acid solution show that the reason for the increase in the reactivity of heat-treated serpentinite at 725 °C and 750 °C with respect to the acidic medium and the degree of magnesium extraction into sulfate solution is the formation of periclase (MgO) in the serpentinite composition after heat treatment of them within a temperature range of 600-750 °C. The results were discussed using data obtained by conducting a thermodynamic evaluation of probable reactions during the thermoacid treatment of serpentinite, phase compressions of heat-treated serpentinite at 600-750 °C, and after its acid treatment at 1.0 M HSO.

摘要

来自日季卡林斯基矿田(哈萨克斯坦日季卡拉市)的蛇纹岩的热酸行为。研究了在600 - 750°C狭窄温度范围内热处理蛇纹岩在硫酸中的溶解特性,在此温度范围内,纤蛇纹石结构构造的晶格在硫酸中被破坏。对热处理后的蛇纹岩在600°C、725°C和750°C下于硫酸溶液中的溶解产物进行的X射线和化学分析表明,在600 - 750°C温度范围内对蛇纹岩进行热处理后,其在725°C和750°C时相对于酸性介质的反应活性增加以及镁提取到硫酸盐溶液中的程度增加的原因是蛇纹岩成分中形成了方镁石(MgO)。利用对蛇纹岩热酸处理过程中可能反应进行热力学评估、600 - 750°C热处理蛇纹岩的相压缩以及在1.0 M H₂SO₄中酸处理后获得的数据对结果进行了讨论。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cbcb/11357560/450d81370f37/molecules-29-03965-g001.jpg

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