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用于增强超级电容器应用的CuO-NiO-CoO纳米复合材料的电化学行为研究

Investigation of the Electrochemical Behavior of CuO-NiO-CoO Nanocomposites for Enhanced Supercapacitor Applications.

作者信息

Kannan Karthik, Chinnaiah Karuppaiya, Gurushankar Krishnamoorthy, Krishnamoorthi Raman, Chen Yong-Song, Murphin Kumar Paskalis Sahaya, Li Yuan-Yao

机构信息

Department of Mechanical Engineering, Advanced Institute of Manufacturing with High-Tech Innovations, National Chung Cheng University, Chia-Yi 621301, Taiwan.

Multifunctional Laboratory, International Research Centre, Kalasalingam Academy of Research and Education, Krishnankoil, Virudhunagar 626126, Tamil Nadu, India.

出版信息

Materials (Basel). 2024 Aug 10;17(16):3976. doi: 10.3390/ma17163976.

Abstract

In the present study, composites incorporating NiO-CoO (NC) and CuO-NiO-CoO (CNC) as active electrode materials were produced through the hydrothermal method and their performance was investigated systematically. The composition, formation, and nanocomposite structure of the fabricated material were characterized by XRD, FTIR, and UV-Vis. The FE-SEM analysis revealed the presence of rod and spherical mixed morphologies. The prepared NC and CNC samples were utilized as supercapacitor electrodes, demonstrating specific capacitances of 262 Fg at a current density of 1 Ag. Interestingly, the CNC composite displayed a notable long-term cyclic stability 84.9%, which was observed even after 5000 charge-discharge cycles. The exceptional electrochemical properties observed can be accredited to the harmonious effects of copper oxide addition, the hollow structure, and various metal oxides. This approach holds promise for the development of supercapacitor electrodes. These findings collectively indicate that the hydrothermally synthesized NC and CNC nanocomposites exhibit potential as high-performance electrodes for supercapacitor applications.

摘要

在本研究中,通过水热法制备了以NiO-CoO(NC)和CuO-NiO-CoO(CNC)作为活性电极材料的复合材料,并对其性能进行了系统研究。通过X射线衍射(XRD)、傅里叶变换红外光谱(FTIR)和紫外可见光谱(UV-Vis)对制备材料的组成、形成过程和纳米复合结构进行了表征。场发射扫描电子显微镜(FE-SEM)分析显示存在棒状和球状混合形态。制备的NC和CNC样品用作超级电容器电极,在电流密度为1 A/g时表现出262 F/g的比电容。有趣的是,CNC复合材料表现出显著的长期循环稳定性,即使在5000次充放电循环后仍能保持84.9%。观察到的优异电化学性能可归因于添加氧化铜、空心结构和各种金属氧化物的协同效应。这种方法为超级电容器电极的开发带来了希望。这些发现共同表明,水热合成的NC和CNC纳米复合材料具有作为超级电容器应用的高性能电极的潜力。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5df1/11355728/14fc32ccdd7c/materials-17-03976-sch001.jpg

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