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高延性地质聚合物混凝土的研究:烘箱热养护条件对力学性能和微观结构发展的影响。

Study on High-Ductility Geopolymer Concrete: The Influence of Oven Heat Curing Conditions on Mechanical Properties and Microstructural Development.

作者信息

Luo Ruihao, Liu Runan, Qin Guang, Jiang Minyang, Wu Yixian, Guo Yongchang

机构信息

School of Civil and Transportation Engineering, Guangdong University of Technology, Guangzhou 510006, China.

Foshan Road and Bridge Supervision Station Corporation Limited, Foshan 528313, China.

出版信息

Materials (Basel). 2024 Aug 12;17(16):4011. doi: 10.3390/ma17164011.

Abstract

Low carbon and high performance have become key trends in the development of construction materials. Understanding the mechanism by which curing conditions affect the mechanical properties of high-ductility geopolymer concrete (HDGC) is of significant importance. This study investigated three sealing curing temperatures (room temperature, 45 °C, and 60 °C) and four curing durations (1 day, 3 days, 5 days, and 7 days), while considering two final curing ages (7 days and 28 days) to explore their effects on the axial tensile and compressive properties of HDGC. The results showed that both 45 °C and 60 °C could improve the brittle failure of HDGC under axial compressive loading. However, curing at 60 °C and for durations longer than 1 day in an oven would catalyze the formation of eight-faced zeolite crystals within the slag-fly ash geopolymer matrix, and it could weaken the matrix's pore structure and subsequently affect the material's later strength development. Nevertheless, oven heat curing enhanced the bridging effect between the fibers and the matrix, partially compensating for the reduction in the initial tensile strength of HDGC. This follows the pseudo-strain-hardening material's saturation cracking criterion to enhance the strain-hardening behavior of HDGC and improve its tensile energy absorption capacity. A curing condition of 45 °C for 5 days is recommended to maximize the ductility of HDGC. This study provides important theoretical support for the design and promotion of green, low-carbon, high-ductility composite materials.

摘要

低碳和高性能已成为建筑材料发展的关键趋势。了解养护条件影响高延性地质聚合物混凝土(HDGC)力学性能的机制具有重要意义。本研究考察了三种密封养护温度(室温、45℃和60℃)和四种养护持续时间(1天、3天、5天和7天),同时考虑了两个最终养护龄期(7天和28天),以探究它们对HDGC轴向拉伸和压缩性能的影响。结果表明,45℃和60℃均可改善HDGC在轴向压缩荷载下的脆性破坏。然而,在60℃烘箱中养护超过1天会催化矿渣-粉煤灰地质聚合物基体中八面沸石晶体的形成,这会削弱基体的孔隙结构,进而影响材料后期强度的发展。尽管如此,烘箱热养护增强了纤维与基体之间的桥接作用,部分弥补了HDGC初始抗拉强度的降低。这遵循了准应变硬化材料的饱和开裂准则,以增强HDGC的应变硬化行为并提高其拉伸能量吸收能力。建议采用45℃养护5天的条件以使HDGC的延性最大化。本研究为绿色、低碳、高延性复合材料的设计与推广提供了重要的理论支持。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/904c/11356627/1e2ecc06acdf/materials-17-04011-g001.jpg

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