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将木质素掺入淀粉基薄膜的益处:简要综述

Benefits of Incorporating Lignin into Starch-Based Films: A Brief Review.

作者信息

Linan Lamia Zuniga, Fakhouri Farayde Matta, Nogueira Gislaine Ferreira, Zoppe Justin, Velasco José Ignacio

机构信息

Department of Chemical Engineering, Federal University of Maranhão (COEQ/UFMA), Av. dos Portugueses 1966, São Luis 65080-805, Brazil.

Poly2 Group, Department of Materials Science and Engineering, Universitat Politècnica de Catalunya (UPC Barcelona Tech), Carrer de Colom 11, 08222 Terrassa-Barcelona, Spain.

出版信息

Polymers (Basel). 2024 Aug 13;16(16):2285. doi: 10.3390/polym16162285.

DOI:10.3390/polym16162285
PMID:39204505
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11359989/
Abstract

Polysaccharides are an excellent renewable source for developing food-packing materials. It is expected that these packages can be an efficient barrier against oxygen; can reduce lipid peroxidation, and can retain the natural aroma of a food commodity. Starch has tremendous potential to be explored in the preparation of food packaging; however, due to their high hydrophilic nature, packaging films produced from starch possess poor protective moisture barriers and low mechanical properties. This scenario limits their applications, especially in humid conditions. In contrast, lignin's highly complex aromatic hetero-polymer network of phenylpropane units is known to play a filler role in polysaccharide films. Moreover, lignin can limit the biodegradability of polysaccharides films by a physical barrier, mainly, and by non-productive bindings. The main interactions affecting lignin non-productive bindings are hydrophobic interactions, electrostatic interactions, and hydrogen-bonding interactions, which are dependent on the total phenolic -OH and -COOH content in its chemical structure. In this review, the use of lignin as a reinforcement to improve the biodegradability of starch-based films in wet environments is presented. Moreover, the characteristics of the used lignins, the mechanisms of molecular interaction among these materials, and the sensitive physicochemical parameters for biodegradability detection are related.

摘要

多糖是开发食品包装材料的优质可再生资源。预计这些包装材料能够有效阻隔氧气;减少脂质过氧化,并能保留食品的天然香气。淀粉在食品包装制备方面具有巨大的开发潜力;然而,由于其高亲水性,由淀粉制成的包装薄膜防潮性差且机械性能低。这种情况限制了它们的应用,尤其是在潮湿环境中。相比之下,木质素由苯丙烷单元组成的高度复杂的芳香族杂聚物网络,在多糖薄膜中起填充作用。此外,木质素主要通过物理屏障以及非生产性结合作用来限制多糖薄膜的生物降解性。影响木质素非生产性结合的主要相互作用是疏水相互作用、静电相互作用和氢键相互作用,这些相互作用取决于其化学结构中总的酚羟基和羧基含量。在本综述中,介绍了使用木质素作为增强剂来提高淀粉基薄膜在潮湿环境中的生物降解性。此外,还阐述了所用木质素的特性、这些材料之间的分子相互作用机制以及生物降解性检测的敏感物理化学参数。

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