Faculty of Biological and Chemical Engineering, Panzhihua University, Panzhihua, 617000, Sichuan, China; Fujian Goshi Green Environmental Protection Technology Development Co., Ltd, Fuqing, 350301, Fujian, China.
Environ Res. 2024 Dec 1;262(Pt 1):119849. doi: 10.1016/j.envres.2024.119849. Epub 2024 Aug 27.
Phosphogypsum(PG) is one of the typical bulk industrial solid wastes generated in the phosphate chemical industry. Due to its huge production volume and immature resource treatment technology, a large amount of PG can only be stored and disposed in slag yards, and its impact on the ecological environment is becoming increasingly significant during long-term storage. Up to now, many researchers have focused their research on PG, with less attention paid to the PG leachate(PG-L). On the basis of the resource utilization of PG, this article analyzed the migration and transformation of pollutants and their impact on the ecological environment during long-term storage of PG. The content of pollutants in PG-L and PG was compared, and it was found that the content of toxic and harmful substances in PG-L was significantly higher than that in PG itself, and the pollution diffusion ability was greater than that of PG, the pollution of PG to the ecological environment is mainly caused by PG-L, indicating that the harmless treatment of PG-L is more urgent than PG. On the basis of traditional leachate treatment methods, a new technology of valuable element recovery and electrochemical synergistic treatment is proposed to achieve high value-added treatment of PG-L.
磷石膏(PG)是磷化工生产中产生的典型大宗工业固体废物之一。由于其产量巨大,资源处理技术不成熟,大量 PG 只能储存在渣场进行处置,其长期储存对生态环境的影响日益显著。迄今为止,许多研究人员都将研究重点放在 PG 上,而对 PG 浸出液(PG-L)的关注较少。本文在 PG 资源利用的基础上,分析了 PG 长期储存过程中污染物的迁移转化及其对生态环境的影响。比较了 PG-L 和 PG 中的污染物含量,发现 PG-L 中有毒有害物质的含量明显高于 PG 本身,且污染扩散能力大于 PG,PG 对生态环境的污染主要是由 PG-L 引起的,这表明 PG-L 的无害化处理比 PG 更为紧迫。在传统浸出液处理方法的基础上,提出了有价元素回收与电化学协同处理的新技术,实现了 PG-L 的高附加值处理。