Utilizing a synergistic strategy that combines electromagnetic and chemical enhancement to analyze the SERS effect of the FeO@GO@Ag on PAHs detection.

A comprehensive understanding of the enhancement mechanism of the substrate material is crucial to ensure the repeatability and functionality of SERS detection technology. Therefore, this study introduces a theoretical analysis method that integrates electromagnetic and chemical enhancement to achieve a comprehensive understanding of the SERS effect on the magnetic composite substrate. The visual model is employed in this study to comprehensively analyze and illustrate the electric field enhancement and optical effects of composite substrate materials. The study also elucidated the adsorption and charge transfer between the substrate material and target molecules. Based on this theory, FeO@GO@Ag material was prepared and used to detect hydrophobic organic molecules such as polycyclic aromatic hydrocarbons (PAHs), with a concentration as low as 0.5 nM. This study comprehensively analyzed the SERS enhancement effect of the composite substrate for the first time, and prepared a magnetic composite substrate material for the detection of hydrophobic organic molecules, opening up a new avenue for theoretical guidance and experimental exploration in SERS detection and analysis.