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一种简便通用的海藻酸钠-硫化铜光热涂层制备方法,用于高效太阳能蒸发。

A facile and versatile preparation method of sodium alginate-copper sulfide photothermal coating for efficient solar evaporation.

机构信息

State Key Lab for Hubei New Textile Materials and Advanced Processing Technology, College of Materials Science & Engineering, College of Textile Science & Engineering, Wuhan Textile University, 430200 Wuhan, China.

State Key Lab for Hubei New Textile Materials and Advanced Processing Technology, College of Materials Science & Engineering, College of Textile Science & Engineering, Wuhan Textile University, 430200 Wuhan, China.

出版信息

Int J Biol Macromol. 2024 Nov;279(Pt 1):135164. doi: 10.1016/j.ijbiomac.2024.135164. Epub 2024 Aug 28.

Abstract

Utilizing inexhaustible solar energy for water purification represents a green and sustainable solution to water scarcity. However, the developments of efficient, inexpensive, convenient and reliable photothermal materials remain a major challenge. Herein, a facile and versatile preparation strategy of sodium alginate (SA)-CuS composite coating with superior adhesion and stability has been proposed toward high-efficiency solar-driven interfacial evaporation. The fabrication process can be quickly completed in aqueous solution with cheap reagents. The SA-CuS coating can be firmly adhered on different substrates, which can withstand rinsing treatment, iterative freeze-thaw cycles as well as high and low pH environments. The SA-CuS coating can convert various substrates into photothermal materials with broad light absorption for desirable solar evaporation because of high CuS loading and rough surface. As a proof of concept, a wood evaporator covered with the SA-CuS coating can achieve a water evaporation rate of ∼2.2 kg m h under one sun illumination, which is superior to most reported wood-based solar evaporators.

摘要

利用取之不尽的太阳能进行水净化是解决水资源短缺问题的绿色可持续方案。然而,开发高效、廉价、方便和可靠的光热材料仍然是一个主要挑战。在此,提出了一种简便通用的制备策略,用于制备具有优异附着力和稳定性的海藻酸钠(SA)-CuS 复合涂层,以实现高效的太阳能驱动界面蒸发。该制造过程可以在水溶液中快速完成,使用廉价的试剂。SA-CuS 涂层可以牢固地附着在不同的基底上,能够承受冲洗处理、反复的冻融循环以及高低 pH 环境。由于高 CuS 负载和粗糙表面,SA-CuS 涂层可以将各种基底转化为具有宽光吸收的光热材料,以实现理想的太阳能蒸发。作为概念验证,覆盖有 SA-CuS 涂层的木材蒸发器在单阳光照下的水蒸发速率约为 2.2 kg m h,优于大多数报道的基于木材的太阳能蒸发器。

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