Progress and challenges in the use of electrochemical oxidation and reduction processes for heavy metals removal and recovery from wastewaters.

Heavy metals-laden industrial wastewater represents both a threat to ecosystems and human health and, in some instances, a potential source of valuable metals however the presence of organic ligands that bind the metals in heavy metal complexes (HMCs) renders metal removal (and, where appropriate, recovery) difficult. Electrochemical-based oxidation and reduction processes represent a potentially promising means of degrading the organic ligands and reducing their ability to retain the metals in solution. In this state-of-the-art review, we provide a comprehensive overview of the current status on use of electrochemical redox technologies for organic ligand degradation and subsequent heavy metal removal and recovery from industrial wastewaters. The principles and degradation mechanism of common organic ligands by various types of electrochemical redox technologies are discussed in this review and consideration given to recent progress in electrode materials synthesis, cell architecture, and operation of electrochemical redox systems. Furthermore, we highlight the current challenges in application of electrochemical redox technologies for treatment of HMC-containing wastewaters including (i) limited understanding of the chemical composition of industrial wastewaters, (ii) constrained mass transfer process affecting the direct/indirect electron transfer, (iii) absence of approaches to convert recovered metal into high-value-added products, and (iv) restricted semi-or full-industrial-scale application of these technologies. Potential strategies for improvement are accordingly provided to guide efforts in addressing these challenges in future research.