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多孔碳/FeO纳米复合材料作为一种新型可磁回收催化剂用于制备多氢喹啉。

Porous carbon/FeO nanocomposite as a new magnetically recoverable catalyst for the preparation of polyhydroquinolines.

作者信息

Goudarziafshar Hamid, Zafari Maryam, Moosavi-Zare Ahmad Reza

机构信息

Department of Chemical Engineering, Hamedan University of Technology Hamedan 65155 Iran

Chemistry Department, College of Sciences, Shiraz University Shiraz 71946-84795 Iran.

出版信息

RSC Adv. 2024 Aug 30;14(38):27565-27574. doi: 10.1039/d4ra05432f. eCollection 2024 Aug 29.

Abstract

A porous carbon/FeO nanocomposite (PC/FeO nanocomposite) was prepared through the pyrolysis of peanut shells as biowaste with ferrous ferric oxide to give a new magnetically recoverable catalyst. In the designed nanocomposite, magnetic iron oxide nanoparticles are properly distributed on the surface and cavities of porous carbon obtained from biomass. Increasing the active surface and magnetic recovery capability results in catalytic synergy, thereby promoting the reaction with an appropriate catalytic effect. The catalytic ability of the porous carbon/FeO nanocomposite as a nanomagnetically recoverable catalyst was successfully tested for the synthesis of polyhydroquinolines.

摘要

通过将花生壳作为生物质废弃物与氧化亚铁进行热解反应,制备了一种多孔碳/FeO纳米复合材料(PC/FeO纳米复合材料),从而得到一种新型的可磁回收催化剂。在所设计的纳米复合材料中,磁性氧化铁纳米颗粒均匀分布在由生物质获得的多孔碳的表面和孔隙中。活性表面积的增加和磁回收能力产生了催化协同作用,从而以适当的催化效果促进反应。成功测试了多孔碳/FeO纳米复合材料作为纳米磁回收催化剂在合成聚氢喹啉方面的催化能力。

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