Bakalis Evangelos, Efthymiopoulos Pavlos, Lugli Francesca, Mitropoulos Athanasios C, Kyzas George Z, Zerbetto Francesco
Dipartimento di Chimica "G.Ciamician", Universita di Bologna, V. F. Selmi 2, 40126, Bologna, Italy.
Hephaestus Laboratory, School of Chemistry, Faculty of Sciences, Democritus University of Thrace, 65404, Kavala, Greece.
Chemphyschem. 2024 Dec 16;25(24):e202400508. doi: 10.1002/cphc.202400508. Epub 2024 Nov 1.
Nanobubbles are sub- micron-sized gas entities that find applications in a wide range of scientific fields. Typically, they are thought to diffuse according to Brownian motion. We report the existence of self-propelled motion of oxygen bulk nanobubbles in ultrapure water at body temperature. Their motion, to a large extent, is self-affine; there are different scaling exponents along the x- and y-axes as well as for the lateral displacement. We use fractal analysis, and we calculate the structure function, the normalised velocity autocorrelation function, the skewness, and the kurtosis. All descriptors attest the existence of a quasi-Gaussian stochastic process, which is classified as fractional Brownian motion. More than 50 % of the trajectories along the x-axis follow superdiffusion, while this amount drops to 30 % for motion along the y-axis as a result of the asymmetry of the field of view.
纳米气泡是亚微米级的气体实体,在广泛的科学领域都有应用。通常,人们认为它们会根据布朗运动进行扩散。我们报告了在体温下超纯水中大量氧气纳米气泡的自推进运动的存在。它们的运动在很大程度上是自仿射的;沿x轴和y轴以及横向位移有不同的标度指数。我们使用分形分析,并计算结构函数、归一化速度自相关函数、偏度和峰度。所有描述符都证明了存在一个准高斯随机过程,该过程被归类为分数布朗运动。沿x轴的轨迹中超过50%遵循超扩散,而由于视野的不对称,沿y轴运动时这一比例降至30%。