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用于多波段防护的仿生分层复合材料

Bioinspired Hierarchical Composite for Multiband Defense.

作者信息

Gao Zhihan, Shi Yunan, Ma Lixia, Du Jiang, Qiu Jun

机构信息

School of Materials Science and Engineering, Tongji University, Shanghai 201804, P. R. China.

Key Laboratory of Advanced Civil Engineering Materials, Ministry of Education, Tongji University, Shanghai 201804, P. R. China.

出版信息

ACS Appl Mater Interfaces. 2024 Sep 18;16(37):49687-49700. doi: 10.1021/acsami.4c11991. Epub 2024 Sep 4.

DOI:10.1021/acsami.4c11991
PMID:39231313
Abstract

The optimization of electromagnetic microwave absorbing (EMA) materials for radar stealth has been a continuous endeavor. However, meeting the defense requirements across multiple-frequency bands in increasingly complex and variable environments remains challenging. Drawing inspiration from the cytoskeleton-organelle structure, we designed and prepared a hierarchical MXene/NiFeO/calcined melamine foam (MNC) composite. The composite exhibits efficient and adjustable microwave absorption, infrared stealth, and solar absorption performance through the synergistic interaction of the components and the spatial effect of its novel microstructure. The composite achieves a minimum reflection loss of -58.57 dB and an effective absorption bandwidth (EAB) of 7.00 GHz, both of which can vary with the thickness. MNC also offers stable infrared stealth performance for heat sources ranging from 37 to 300 °C and high solar absorptivity up to 96.2%, promoting ambient-temperature-adaptive infrared stealth through electricity-sunlight cooperative regulation. With exceptional environmental adaptability characteristics such as photothermal conversion, lightness, elasticity, and hydrophobicity, the MNC composite holds promise as a multispectrum defense material for radar, infrared, and visible light for various forms of equipment, clothing, and wearables in harsh conditions.

摘要

用于雷达隐身的电磁微波吸收(EMA)材料的优化一直是一项持续的努力。然而,在日益复杂多变的环境中满足多频段的国防需求仍然具有挑战性。受细胞骨架-细胞器结构的启发,我们设计并制备了一种分级的MXene/NiFeO/煅烧三聚氰胺泡沫(MNC)复合材料。通过各组分的协同相互作用及其新型微观结构的空间效应,该复合材料展现出高效且可调节的微波吸收、红外隐身和太阳能吸收性能。该复合材料实现了-58.57 dB的最小反射损耗和7.00 GHz的有效吸收带宽(EAB),两者均可随厚度变化。MNC还为37至300°C的热源提供稳定的红外隐身性能以及高达96.2%的高太阳能吸收率,通过电-阳光协同调控促进环境温度自适应红外隐身。凭借光热转换、轻质、弹性和疏水性等卓越的环境适应性特征,MNC复合材料有望成为用于恶劣条件下各种形式的设备、服装和可穿戴设备的雷达、红外和可见光多光谱防护材料。

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