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精密甲醇传感:整合光学传感器的化学见解以增强检测

Precision Methanol Sensing: Integrating Chemical Insights of Optical Sensors for Enhanced Detection.

作者信息

Deoghoria Amit K, Dey Nilanjan

机构信息

Department of Chemistry, BITS-Pilani Hyderabad Campus, Jawahar Nagar, Hyderabad, Telangana, 500078, India.

出版信息

J Fluoresc. 2025 Jul;35(7):4959-4971. doi: 10.1007/s10895-024-03860-0. Epub 2024 Sep 5.

DOI:10.1007/s10895-024-03860-0
PMID:39235655
Abstract

Methanol has become a very important part of many industries, ranging from chemical production and pharmaceuticals to automotive and electronics manufacturing as a result of which methanol usage has spiked in recent years. But this exponential increase asks for precise detection methods as methanol has not only detrimental effects on environment but it is very dangerous to human health even if consumed in a minute amount .This paper will explore the unique physical and chemical properties of methanol which can be exploited to make it a target for different mechanisms such as H-Bonding, induced self-assembly, Internal Charge Transfer (ICT), Aggregation-induced emission (AIE), conformational flexibility, keto-enol tautomerization, adsorption etc. by various small molecule and nano-particles. Informative studies on small molecules involves functionalized pentacenequinone derivatives, luminogens, ligands and fluorescent probes which can be used to detect methanol by change in color or intensity which can be easily detected in real time and is portable. On the other hand, nanoparticle-based probes reveal the use of materials like chitosan/zinc, sulfide composites, Quantum Dots (QDs) hybrids, graphene polyoxides, Ag-LaFeO etc. which provides with selective and sensitive methanol optical and conductometric sensing. This paper acknowledges the contributions of various studies and researchers who contributed to advancing the field of methanol sensing, providing a foundation for future developments.

摘要

甲醇已成为许多行业非常重要的一部分,涵盖从化学生产、制药到汽车和电子制造等领域,因此近年来甲醇的用量激增。但这种指数级增长需要精确的检测方法,因为甲醇不仅对环境有不利影响,而且即使微量摄入对人体健康也非常危险。本文将探讨甲醇独特的物理和化学性质,这些性质可被利用,使甲醇成为各种小分子和纳米颗粒通过氢键、诱导自组装、分子内电荷转移(ICT)、聚集诱导发光(AIE)、构象灵活性、酮 - 烯醇互变异构、吸附等不同机制作用的目标。关于小分子的信息性研究涉及功能化并五苯醌衍生物、发光体、配体和荧光探针,它们可通过颜色或强度变化来检测甲醇,这种变化可实时轻松检测且便于携带。另一方面,基于纳米颗粒的探针展示了壳聚糖/锌、硫化物复合材料、量子点(QD)杂化物、石墨烯氧化物、Ag - LaFeO等材料的应用,这些材料可提供选择性和灵敏的甲醇光学和电导传感。本文认可了为推进甲醇传感领域做出贡献的各种研究和研究人员,为未来发展奠定了基础。

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Empirical Hydrogen Bonding Donor (HBD) Parameters of Organic Solvents Using Solvatochromic Probes - A Critical Evaluation.使用溶剂探针的有机溶剂经验氢键给体(HBD)参数 - 批判性评估。
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Engaging Dynamic Surfactant Assemblies in Improving Metal Ion Sensitivity of a 1,4,7-Triazacyclononane-Based Receptor: Differential Optical Response for Cysteine and Histidine.
利用动态表面活性剂组装体提高基于1,4,7-三氮杂环壬烷的受体对金属离子的敏感性:对半胱氨酸和组氨酸的差分光学响应
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