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通过高压气相生长(HVPG)技术制备的氧化锌纳米材料在一氧化碳气体传感器方面的应用前景广阔。

Promising CO gas sensor application of zinc oxide nanomaterials fabricated via HVPG technique.

作者信息

Haygood Klaud Jenssen F, Harnany Dinny, Santos Gil Nonato C, Muflikhun Muhammad Akhsin

机构信息

Physics Department, De La Salle University, Manila, Philippines.

Mechanical Engineering Department, Institut Teknologi Sepuluh Nopember, Surabaya, Indonesia.

出版信息

Heliyon. 2024 Aug 22;10(17):e36692. doi: 10.1016/j.heliyon.2024.e36692. eCollection 2024 Sep 15.

Abstract

Highly effective gas sensors for detecting a range of hazardous and toxic gases were successfully applied in the present study using Zinc oxide (ZnO) nanomaterials. In this work, the horizontal vapor phase growth (HVPG) technique was perfectly capable of the synthesis of zinc oxide (ZnO) nanomaterials. The effect of the growth time with different dwell times was discussed by comparing the SEM-EDX analysis and photoluminescence characterization of the samples. Magnetic field (AMF) was also incorporated to determine the effect of AMF on the synthesis of ZnO nanomaterials. The results showed that the ZnO nanorods and root-like shapes are formed with more than 5 μm length and a few nm diameters. The optimum parameter showed the sensors are shiner than the less effective sensor when applied. The introduction of an external magnetic field led to a reduced energy band gap by a maximum of 15 %. The non-AMF band gap energy value is observed to be between 3.51 and 3.58 eV, while the value obtained using AMF is found to be between 2.94 and 3.22 eV. During the CO gas sensor test, AMF ZnO nanomaterial samples exhibited higher voltage and gradient compared to non-AMF samples.

摘要

在本研究中,使用氧化锌(ZnO)纳米材料成功应用了用于检测一系列有害和有毒气体的高效气体传感器。在这项工作中,水平气相生长(HVPG)技术完全能够合成氧化锌(ZnO)纳米材料。通过比较样品的扫描电子显微镜-能谱分析(SEM-EDX)和光致发光表征,讨论了不同停留时间的生长时间的影响。还引入了交变磁场(AMF)来确定AMF对ZnO纳米材料合成的影响。结果表明,形成了长度超过5μm、直径为几纳米的ZnO纳米棒和根状形状。最佳参数表明,应用时传感器比效果较差的传感器更灵敏。引入外部磁场导致能带隙最大降低了15%。观察到非AMF能带隙能量值在3.51至3.58 eV之间,而使用AMF获得的值在2.94至3.22 eV之间。在CO气体传感器测试期间,与非AMF样品相比,AMF ZnO纳米材料样品表现出更高的电压和梯度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f877/11386046/60acf2e1d4ad/ga1.jpg

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