Global groundwater contamination by Arsenic (As) presents a grave danger to the health of living beings and wildlife, demanding comprehensive remediation strategies. This review delves into the complex landscape of arsenic remediation, encompassing its chemical forms, occurrences, sources, and associated health risks. Advanced techniques, notably biomass-derived adsorbents, emerge as promising and cost-effective solutions. The exploration spans preparing and modifying biomass-derived adsorbents, unraveling their adsorption capacity, influencing factors, isotherms, kinetics, and thermodynamics. Noteworthy attention is given to plant-agricultural waste, algal-fungal-bacterial, and iron-modified biomass-derived adsorbents. The comprehensive discussion of the adsorption mechanism highlights the efficacy of low-cost biomass, particularly from plant, animal, and agricultural residues, offering a sustainable remedy for arsenic removal. This insightful review contributes to the understanding of evolving technologies essential for addressing arsenic contamination in wastewater, emphasizing the potential of renewable biomaterials in advancing efficient remediation practices.