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用于高效CO还原的β-GaO-rGO光催化剂的协同增强及基本机理探索

Synergistic augmentation and fundamental mechanistic exploration of β-GaO-rGO photocatalyst for efficient CO reduction.

作者信息

Jung Hye-In, Choi Hangyeol, Song Yu-Jin, Kim Jung Han, Yoon Yohan

机构信息

Korea Aerospace University, Department of Materials Engineering Goyang Republic of Korea

Dong-A University, Department of Materials Science and Engineering Busan Republic of Korea.

出版信息

Nanoscale Adv. 2024 Jul 15;6(18):4611-4624. doi: 10.1039/d4na00408f. eCollection 2024 Sep 10.

Abstract

We explore the novel photodecomposition capabilities of β-GaO when augmented with reduced graphene oxide (rGO). Employing real-time spectroscopy, this study unveils the sophisticated mechanisms of photodecomposition, identifying an optimal 1 wt% β-GaO-rGO ratio that substantially elevates the degradation efficiency of Methylene Blue (MB). Our findings illuminate a direct relationship between the photocatalyst's composition and its performance, with the quantity of rGO synthesis notably influencing the catalyst's morphology and consequently, its photodegradation potency. The 1 wt% β-GaO-rGO composition stands out in its class, showing a notable 4.7-fold increase in CO production over pristine β-GaO and achieving CO selectivity above 98%. This remarkable performance is a testament to the significant improvements rendered by our novel rGO integration technique. Such promising results highlight the potential of our custom-designed β-GaO-rGO photocatalyst for critical environmental applications, representing a substantial leap forward in photocatalytic technology.

摘要

我们探索了用还原氧化石墨烯(rGO)增强的β-GaO的新型光分解能力。本研究采用实时光谱法揭示了光分解的复杂机制,确定了1 wt%的β-GaO-rGO最佳比例,该比例显著提高了亚甲基蓝(MB)的降解效率。我们的研究结果揭示了光催化剂的组成与其性能之间的直接关系,rGO的合成量显著影响催化剂的形态,进而影响其光降解能力。1 wt%的β-GaO-rGO组成在同类中脱颖而出,与原始β-GaO相比,CO产量显著增加4.7倍,CO选择性达到98%以上。这一卓越性能证明了我们新型rGO集成技术带来的显著改进。这些有前景的结果凸显了我们定制设计的β-GaO-rGO光催化剂在关键环境应用中的潜力,代表了光催化技术的重大飞跃。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4b97/11385812/e74ea25e664d/d4na00408f-f1.jpg

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