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简化用于材料测试的钙钛矿太阳能电池制造:如何借助三维打印的电池支架使用未蚀刻的基板。

Simplifying perovskite solar cell fabrication for materials testing: how to use unetched substrates with the aid of a three-dimensionally printed cell holder.

作者信息

Valdez García Joaquín, Hadadian Mahboubeh, Nizamov Rustem, Mäkinen Paavo, Lamminen Noora, Vivo Paola, Miettunen Kati

机构信息

Department of Mechanical and Materials Engineering, Faculty of Technology, University of Turku, Vesilinnantie 5, Turku FI-20500, Finland.

Hybrd Solar Cells, Faculty of Engineering and Natural Sciences, Tampere University, P. O. Box 541, Tampere FI 33014, Finland.

出版信息

R Soc Open Sci. 2024 Sep 11;11(9):241012. doi: 10.1098/rsos.241012. eCollection 2024 Sep.

DOI:10.1098/rsos.241012
PMID:39263454
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11387052/
Abstract

This work demonstrates that unetched substrates can be reliably used in perovskite solar cell (PSC) fabrication. Chemical etching and laser patterning of the bottom electrodes are time- and resource-consuming processes. In particular, when testing novel conductive substrate materials, such as metallic or bio-based substrates, etching or patterning could be entirely unfeasible or could require significant process optimization. Avoiding these steps could accelerate research on PSCs, yet the literature shows no attempts to override these steps. Here, PSCs were fabricated and characterized using three-dimensionally printed holders with spring-loaded pins. We show that devices made on unetched substrates have, on average, a similar performance to those made on etched substrates (16 ± 1% and 16.0 ± 0.7%, respectively). Our study provides a new strategy for fabricating PSCs, particularly when etching and laser patterning are impractical.

摘要

这项工作表明,未蚀刻的衬底可可靠地用于钙钛矿太阳能电池(PSC)制造。底部电极的化学蚀刻和激光图案化是耗时且耗费资源的过程。特别是在测试新型导电衬底材料(如金属或生物基衬底)时,蚀刻或图案化可能完全不可行,或者可能需要大量的工艺优化。避免这些步骤可以加速PSC的研究,但文献表明尚无尝试跳过这些步骤。在此,使用带有弹簧销的三维打印夹具制造并表征了PSC。我们表明,在未蚀刻衬底上制造的器件平均性能与在蚀刻衬底上制造的器件相似(分别为16±1%和16.0±0.7%)。我们的研究为制造PSC提供了一种新策略,特别是在蚀刻和激光图案化不可行的情况下。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/66df784d63b1/rsos.241012.f005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/7fc1fc244536/rsos.241012.f001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/d5631d2a5fd1/rsos.241012.f002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/85bb48a0b652/rsos.241012.f003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/8e9aa9ba0a25/rsos.241012.f004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/66df784d63b1/rsos.241012.f005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/7fc1fc244536/rsos.241012.f001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/d5631d2a5fd1/rsos.241012.f002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/85bb48a0b652/rsos.241012.f003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/8e9aa9ba0a25/rsos.241012.f004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9938/11387052/66df784d63b1/rsos.241012.f005.jpg

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Impedance Spectroscopy of Metal Halide Perovskite Solar Cells from the Perspective of Equivalent Circuits.从等效电路角度看金属卤化物钙钛矿太阳能电池的阻抗谱
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