Crystal structure of propane-1,3-diaminium squarate dihydrate.

Propane-1,3-diaminium squarate dihydrate, CHN ·CO ·2HO, results from the proton-transfer reaction of propane-1,3-di-amine with squaric acid and subsequent crystallization from aqueous medium. The title compound crystallizes in the tetra-gonal crystal system (space group 4) with = 2. The squarate dianion belongs to the point group and contains a crystallographic fourfold axis. The propane-1,3-diaminium dication exhibits a -symmetric all- conformation and resides on a special position with 2 site symmetry. The orientation of the propane-1,3-diaminium ions makes the crystal structure polar in the axis direction. The solid-state supra-molecular structure features a triperiodic network of strong hydrogen bonds of the N-H⋯O and O-H⋯O types.