Iftikhar Tuba, Rosnes Mali H
Department of Chemistry, University of Bergen, Bergen, Norway.
Front Chem. 2024 Aug 29;12:1447623. doi: 10.3389/fchem.2024.1447623. eCollection 2024.
Polyoxometalates (POMs) are a class of compounds known for the vast range of tunable structures and properties available, leading to applications in areas such as catalysis, energy, and advanced medicine. The ability to covalently functionalize POMs with organic components has been investigated extensively to tune the physical and chemical properties of the resulting hybrid materials. These hybrids, where the organic entity is covalently attached to the POM-core ( hybrid POMs) result in a vast library of promising customizable catalytic systems, displaying tunable properties with a high level of synergy between the polyanion and the organic component. A number of hybrids have been investigated for a wide range of catalytic applications, and here, we give a brief overview of hybrids of the p-block elements and their applications in catalysis.
多金属氧酸盐（POMs）是一类以具有广泛可调结构和性质而闻名的化合物，这使得它们在催化、能源和先进医学等领域得到应用。人们对用有机成分将POMs共价功能化以调节所得杂化材料的物理和化学性质进行了广泛研究。在这些杂化材料中，有机实体共价连接到POM核上（杂化POMs），形成了大量有前景的可定制催化体系库，显示出可调性质，且聚阴离子与有机成分之间具有高度协同作用。许多杂化材料已被研究用于广泛的催化应用，在此，我们简要概述p区元素的杂化材料及其在催化中的应用。
