Kuramochi Satoshi, Cameron Jamie M, Fukui Tomoya, Jones Kieran D, Argent Stephen P, Kusaka Shinpei, Shiraishi Ryo, Tamaki Yusuke, Yatsu Taiki, Shiga Takuya, Ishitani Osamu, Oshio Hiroki, Newton Graham N
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennoudai 1-1-1, Tsukuba, Ibaraki, 305-8571, Japan.
GSK Carbon Neutral Laboratories for Sustainable Chemistry, School of Chemistry, University of Nottingham, Nottingham, NG7 2TU, UK.
Chem Commun (Camb). 2023 Sep 7;59(72):10801-10804. doi: 10.1039/d3cc02138f.
A multi-component coordination compound, in which ruthenium antenna complexes are connected to a polyoxotungstate core is presented. This hybrid cluster effectively promotes the electrochemical conversion of CO to C1 feedstocks, the selectivity of which can be controlled by the acidity of the media.
本文介绍了一种多组分配位化合物，其中钌天线配合物连接到多金属氧酸盐核上。这种混合簇有效地促进了CO向C1原料的电化学转化，其选择性可通过介质的酸度来控制。
