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在1M硫酸溶液中制备的用于渗碳奥氏体球墨铸铁的席夫碱的腐蚀电位及理论研究。

Corrosion potential and theoretical studies of fabricated Schiff base for carbidic austempered ductile iron in 1M HSO solution.

作者信息

Gaber Ghalia A, Mohamed Lamiaa Z, Aly Hayam A, Hosny Shimaa

机构信息

Department of Chemistry, Faculty of Science (Girls), Al-Azhar University, Yousef Abbas Str., P.O. Box: 11754, Nasr City, Cairo, Egypt.

Mining, Petroleum, and Metallurgical Engineering Department, Faculty of Engineering, Cairo University, Giza, 12613, Egypt.

出版信息

BMC Chem. 2024 Sep 13;18(1):170. doi: 10.1186/s13065-024-01278-0.

Abstract

In this body of work, a chemical known as 2-cyano-N-(4-morpholino benzyl dine) acetohydrazide (CMBAH) is explored for its ability to suppress the carbidic austempered ductile iron (CADI) corrosion in 1M HSO. Density functional theory was used in experiments and theoretical investigations to investigate the inhibiting impact. The corrosion of CADI alloys in 1M HSO produced a corrosion resistance superior to that of CADI heat treatment (H.T.). As-cast carbidic ductile iron (CDI) 4 alloy with 1.5%t Cr-Nb has a corrosion rate (C.R.) of 11.69 mm/year, which drops to 5.31 mm/year at HT-275 °C and 6.13 mm/year at HT-375 °C. When describing the adsorption of inhibitors, the Langmuir adsorption isotherm is the most effective method. The findings of the G show that the inhibition was induced mainly by the physisorption on the surface CADI alloys. In addition to this, it was found that the results of the experiments and the hypotheses were largely harmonious with one another. The formation of protective layers on the CADI surfaces is also visible in the images captured by the SEM. In 1M HSO, these Schiff base inhibitors effectively prevent corrosion caused by CADI. However, the combination of inhibitors leads to a fine microstructure with ausferrite and narrow ferrite needles, promoting corrosion resistance. The CADI needles rated an upper ausferritic microstructure with wide ferrite needles.

摘要

在这项工作中,对一种名为2-氰基-N-(4-吗啉代苄叉二胺)乙酰肼(CMBAH)的化学物质抑制1M硫酸中渗碳体等温淬火球墨铸铁(CADI)腐蚀的能力进行了研究。在实验和理论研究中使用密度泛函理论来研究其抑制作用。CADI合金在1M硫酸中的腐蚀产生的耐腐蚀性优于CADI热处理(H.T.)。含1.5% Cr-Nb的铸态渗碳体球墨铸铁(CDI) 4合金的腐蚀速率(C.R.)为11.69毫米/年,在275℃热处理时降至5.31毫米/年,在375℃热处理时降至6.13毫米/年。在描述抑制剂的吸附时,朗缪尔吸附等温线是最有效的方法。G的研究结果表明,抑制作用主要是由表面CADI合金上的物理吸附引起的。除此之外,还发现实验结果和假设在很大程度上相互一致。在扫描电子显微镜拍摄的图像中也可以看到CADI表面形成了保护层。在1M硫酸中,这些席夫碱抑制剂有效地防止了CADI引起的腐蚀。然而,抑制剂的组合导致了具有奥氏体铁素体和窄铁素体针的精细微观结构,提高了耐腐蚀性。CADI针评级为具有宽铁素体针的上部奥氏体铁素体微观结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b7ea/11401432/c8656658b0df/13065_2024_1278_Fig1_HTML.jpg

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