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用石墨烯纳米片和炭黑纳米颗粒增强聚乳酸性能:3D打印和注塑成型样品的电学和力学特性研究

Enhancing Polylactic Acid Properties with Graphene Nanoplatelets and Carbon Black Nanoparticles: A Study of the Electrical and Mechanical Characterization of 3D-Printed and Injection-Molded Samples.

作者信息

Giner-Grau Salvador, Lazaro-Hdez Carlos, Pascual Javier, Fenollar Octavio, Boronat Teodomiro

机构信息

Textile Industry Research Association (AITEX), Plaza Emilio Sala, 1, 03801 Alcoy, Spain.

Instituto Universitario de Investigación de Tecnología de Materiales (IUITM), Universitat Politècnica de València (UPV), Plaza Ferrándiz y Carbonell 1, 03801 Alcoy, Spain.

出版信息

Polymers (Basel). 2024 Aug 29;16(17):2449. doi: 10.3390/polym16172449.

DOI:10.3390/polym16172449
PMID:39274081
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11398012/
Abstract

This study investigates the enhancement of polylactic acid (PLA) properties through the incorporation of graphene nanoplatelets (GNPs) and carbon black (CB) for applications in 3D printing and injection molding. The research reveals that GNPs and CB improve the electrical conductivity of PLA, although conductivity remains within the insulating range, even with up to 10% wt of nanoadditives. Mechanical characterization shows that nanoparticle addition decreases tensile strength due to stress concentration effects, while dispersants like polyethylene glycol enhance ductility and flexibility. This study compares the properties of materials processed by injection molding and 3D printing, noting that injection molding yields isotropic properties, resulting in better mechanical properties. Thermal analysis indicates that GNPs and CB influence the crystallization behavior of PLA with small changes in the melting behavior. Dynamic Mechanical Thermal Analysis (DMTA) results show how the glass transition temperature and crystallization behavior fluctuate. Overall, the incorporation of nanoadditives into PLA holds potential for enhanced performance in specific applications, though achieving optimal conductivity, mechanical strength, and thermal properties requires careful optimization of nanoparticle type, concentration, and dispersion methods.

摘要

本研究通过添加石墨烯纳米片(GNPs)和炭黑(CB)来研究聚乳酸(PLA)性能的增强,以用于3D打印和注塑成型应用。研究表明,GNPs和CB提高了PLA的电导率,尽管即使添加高达10%重量的纳米添加剂,电导率仍处于绝缘范围内。力学表征显示,由于应力集中效应,添加纳米颗粒会降低拉伸强度,而聚乙二醇等分散剂可提高延展性和柔韧性。本研究比较了通过注塑成型和3D打印加工的材料的性能,指出注塑成型产生各向同性性能,从而具有更好的力学性能。热分析表明,GNPs和CB会影响PLA的结晶行为,同时熔融行为有微小变化。动态机械热分析(DMTA)结果显示了玻璃化转变温度和结晶行为是如何波动的。总体而言,将纳米添加剂加入PLA在特定应用中具有提高性能的潜力,不过要实现最佳的导电性、机械强度和热性能,需要仔细优化纳米颗粒类型、浓度和分散方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/059e2045f5b7/polymers-16-02449-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/8626cbfb499a/polymers-16-02449-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/27d15b6ed570/polymers-16-02449-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/db8c87888311/polymers-16-02449-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/8ad9475ed463/polymers-16-02449-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/ff6515df928e/polymers-16-02449-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/6f7b826329e4/polymers-16-02449-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/059e2045f5b7/polymers-16-02449-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/8626cbfb499a/polymers-16-02449-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/27d15b6ed570/polymers-16-02449-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/db8c87888311/polymers-16-02449-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/8ad9475ed463/polymers-16-02449-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/ff6515df928e/polymers-16-02449-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/6f7b826329e4/polymers-16-02449-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cd0c/11398012/059e2045f5b7/polymers-16-02449-g007.jpg

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本文引用的文献

1
Effect of Plasticization/Annealing on Thermal, Dynamic Mechanical, and Rheological Properties of Poly(Lactic Acid).增塑/退火对聚乳酸热性能、动态力学性能和流变性能的影响
Polymers (Basel). 2024 Apr 3;16(7):974. doi: 10.3390/polym16070974.
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Novel Epoxidized Brazil Nut Oil as a Promising Plasticizing Agent for PLA.新型环氧化巴西坚果油作为聚乳酸有前景的增塑剂
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