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激光功率对基于激光直接能量沉积制备的WC-12Co复合涂层微观结构及性能的影响

Effect of Laser Power on Microstructure and Properties of WC-12Co Composite Coatings Deposited by Laser-Based Directed Energy Deposition.

作者信息

Li Wen, Yang Husen, Liu Yichun, Li Fengxian, Yi Jianhong, Eckert Jürgen

机构信息

Faculty of Material Science and Engineering, Kunming University of Science and Technology, Kunming 650093, China.

Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Jahnstraße 12, A-8700 Leoben, Austria.

出版信息

Materials (Basel). 2024 Aug 26;17(17):4215. doi: 10.3390/ma17174215.

Abstract

During the laser-based directed energy deposition (DED-LB) processing, a WC-12Co composite coating with high hardness and strong wear resistance was successfully prepared on a 316L stainless steel substrate by adopting a high-precision coaxial powder feeding system using a spherical WC-12Co composite powder, which showed a large number of dendritic carbides and herringbone planar crystals on the substrate-binding interface. The influences of laser power on microstructural and mechanical properties (e.g., hardness, friction resistance) of WC-12Co composite surfaces were investigated. The results show that laser power has a significant effect on determining the degree of Co phase melting around the WC particles and the adhesion strength between the matrix and the coating. Lower laser power does not meet the melting requirements of WC particles, thus weakening the molding quality of the composite coating. At high laser power, it is possible to dissolve the WC particles and melt the metal powder between the particles, thus improving the material properties. The laser power increased from 700 W to 1000 W and the average hardness of the coating surface gradually increased from 1166.33 HV to 1395.70 HV, which is about 4-5 times higher than the average hardness of the substrate (about 281.76 HV). In addition, the coatings deposited at 1000 W showed better wear resistance. This work shows that the processing parameters during laser-directed energy deposition can be optimized to prepare WC-12Co composite coatings with excellent mechanical properties.

摘要

在基于激光的定向能量沉积(DED-LB)加工过程中,采用高精度同轴送粉系统,使用球形WC-12Co复合粉末,在316L不锈钢基体上成功制备了具有高硬度和强耐磨性的WC-12Co复合涂层,该涂层在基体结合界面上呈现出大量树枝状碳化物和人字形平面晶体。研究了激光功率对WC-12Co复合表面微观结构和力学性能(如硬度、摩擦阻力)的影响。结果表明,激光功率对确定WC颗粒周围Co相的熔化程度以及基体与涂层之间的结合强度有显著影响。较低的激光功率不能满足WC颗粒的熔化要求,从而削弱了复合涂层的成型质量。在高激光功率下,有可能溶解WC颗粒并熔化颗粒之间的金属粉末,从而改善材料性能。激光功率从700 W增加到1000 W时,涂层表面的平均硬度从1166.33 HV逐渐增加到1395.70 HV,约为基体平均硬度(约281.76 HV)的4-5倍。此外,在1000 W下沉积的涂层表现出更好的耐磨性。这项工作表明,可以优化激光定向能量沉积过程中的工艺参数,以制备具有优异力学性能的WC-12Co复合涂层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3074/11396090/613d54f2b4bf/materials-17-04215-g001.jpg

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