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用于环境修复的基于胆固醇的有机凝胶剂:在去除有毒纺织染料和溢油回收中的应用

Cholesterol Based Organogelators in Environmental Remediation: Applications in Removal of Toxic Textile Dyes and Oil Spill Recovery.

作者信息

Singha Anindita, Khan Meheboob, Roy Sumita

机构信息

Department of Chemistry and Chemical Technology, Vidyasagar University, Paschim, Medinipur 721 102, India.

出版信息

Langmuir. 2024 Sep 14. doi: 10.1021/acs.langmuir.4c02289.

Abstract

Oil spills in the ocean and textile dyes have a catastrophic impact on the environment, economy, and ecosystem. Phase-selective organic gelator dye sorption and oil separation for oil adsorption should meet certain criteria such as facile synthesis, low cost, effective gelation, and recyclability. This study has discovered that an aliphatic chain synthetic amphiphile based on cholesterol can produce organogels in a variety of organic solvents. Numerous methods, such as X-ray diffraction, Fourier-transform infrared spectroscopy, high-resolution scanning electron microscopy, and rheology, have been used extensively to examine and describe these organogels. An environmentally acceptable technique for achieving hazardous dye separation is presented here. For the sustainable filtration of dye-contaminated water, a new, straightforward, one-step method driven by gravitational force has been employed by using a gel column. This approach has shown excellent stability and reusability with repeated use, and it is easily scalable for the effective removal of a wide range of hazardous dyes. Furthermore, because the oil fraction was absorbed in the gel, the study showed how well it might be used to apply phase selectivity to separate the oil-water mixture from marine accidents. Furthermore, a straightforward distillation method can be used to quantitatively recover the oils contained in the gel and gelator molecules in phase-selective gelation. This low-tech, ecofriendly, and highly effective method also offers valuable insights into the development of advanced materials for separating toxic dyes and oil from water.

摘要

海洋中的石油泄漏和纺织染料对环境、经济和生态系统都有着灾难性的影响。用于油吸附的相选择性有机凝胶剂染料吸附和油分离应满足某些标准,如合成简便、成本低、有效凝胶化和可回收性。本研究发现,一种基于胆固醇的脂肪族链合成两亲物能在多种有机溶剂中形成有机凝胶。许多方法,如X射线衍射、傅里叶变换红外光谱、高分辨率扫描电子显微镜和流变学,已被广泛用于研究和描述这些有机凝胶。本文提出了一种环境可接受的实现有害染料分离的技术。为了对受染料污染的水进行可持续过滤,通过使用凝胶柱采用了一种由重力驱动的新型、简单的一步法。这种方法在重复使用时表现出了出色的稳定性和可重复使用性,并且易于扩展以有效去除多种有害染料。此外,由于油相被吸收在凝胶中,该研究展示了其在应用相选择性从海洋事故中分离油水混合物方面的良好效果。此外,在相选择性凝胶化过程中,可以使用一种简单的蒸馏方法来定量回收凝胶中所含的油和凝胶剂分子。这种低技术、环保且高效的方法也为开发从水中分离有毒染料和油的先进材料提供了有价值的数据。

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