Yaroshenko Vitaly, Larin Artem, Syubaev Sergey, Vazhenin Ivan, Kustov Pavel, Dolgintsev Dmitry, Ageev Eduard, Gurbatov Stanislav, Maksimova Alina, Novikova Kristina, Babin Sergey, Kozlov Aleksey, Dostovalov Alexandr, Kuchmizhak Aleksandr, Zuev Dmitry
School of Physics and Engineering, ITMO University, 197101 St. Petersburg, Russia.
Institute of Automation and Control Processes, Far Eastern Branch of RAS, Vladivostok 690041, Russia.
J Phys Chem Lett. 2024 Sep 26;15(38):9714-9722. doi: 10.1021/acs.jpclett.4c02051. Epub 2024 Sep 16.
Authentication of a product's originality by anticounterfeiting labels represents a crucial point toward protection against forgery. Fast and scalable fabrication methods of original labels with a high degree of protection are in high demand for the protection of valuable goods. Here, we propose a simple strategy for fabrication of hidden security tags with IR luminescent readout by the direct femtosecond laser patterning of silicon-erbium-silicon sandwiched thin films. The choice of laser processing parameters makes possible the creation of random or quasi-regular self-organized surface nanotextures. The controlled laser-driven oxidation accompanying this process provides simultaneous regulation of the film's optical properties and spontaneous emission yield of the embedded Er atoms. The regimes are detected when optically similar patterned areas demonstrate different Er emission intensities, allowing us to create hidden security tags with facile readout at the C-band telecommunication wavelengths. The obtained results take another step toward the application of IR-luminescent erbium-based anticounterfeiting labels for covert and/or forensic security levels.
通过防伪标签对产品的原创性进行认证是防止伪造的关键环节。对于保护贵重物品而言,快速且可扩展的高保护度原创标签制造方法需求迫切。在此,我们提出一种简单策略,通过对硅 - 铒 - 硅夹心薄膜进行直接飞秒激光图案化来制造具有红外发光读出功能的隐藏安全标签。激光加工参数的选择使得创建随机或准规则的自组织表面纳米纹理成为可能。伴随此过程的可控激光驱动氧化同时调节了薄膜的光学性质以及嵌入铒原子的自发发射率。当光学上相似的图案区域表现出不同的铒发射强度时,检测到这些状态,这使我们能够创建在C波段电信波长处易于读出的隐藏安全标签。所获得的结果朝着将基于红外发光铒的防伪标签应用于隐蔽和/或法医安全级别又迈进了一步。