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锶离子在新型纳米多孔铝硼硅酸盐基质上的高效吸附及稳固固定

Efficient sorption and secure immobilization of strontium ions onto nanoporous alumino-borosilicate as a new matrix.

作者信息

Abbasi Ali, Avanes Armen, Davarkhah Reza, Yadollahi Ali, Sepehrian Hamid

机构信息

Department of Chemistry, University of Maragheh, P.O. Box 5518183111, Maragheh, Iran.

Nuclear Science and Technology Research Institute, P. O. Box 11365/8486, Tehran, Iran.

出版信息

Sci Rep. 2024 Sep 16;14(1):21617. doi: 10.1038/s41598-024-72126-3.

Abstract

The objective behind developing the nanoporous alumino-borosilicate (AlBS) was to remove strontium ion (Sr) from liquid waste and subsequently stabilize it. The sorption capacity of the nanoporous AlBS was assessed in relation to various experimental factors, including contact time, temperature, initial pH solution, and initial concentration of Sr ions. According to the obtained results, nanoporous AlBS shows a maximum Sr sorption capacity of 163.08 mg/g. In order to achieve stable immobilization of the sorbed Sr ions, heat treatments at different temperatures were applied to the Sr-containing nanoporous AlBS. Various eluents were used in the leach tests to examine the Sr ions leaching from heat-treated materials. Only 3.43% of the Sr ions initially adsorbed in the nanoporous AlBS matrix was washed out with 1 M sodium chloride eluent, showing that heating the sample to around 1100 °C successfully trapped Sr ions in the nanoporous AlBS matrix.

摘要

开发纳米多孔铝硼硅酸盐(AlBS)的目的是从液体废物中去除锶离子(Sr)并使其稳定化。针对各种实验因素评估了纳米多孔AlBS的吸附能力,这些因素包括接触时间、温度、初始溶液pH值和Sr离子的初始浓度。根据所得结果,纳米多孔AlBS的最大Sr吸附容量为163.08 mg/g。为了实现吸附的Sr离子的稳定固定化,对含Sr的纳米多孔AlBS进行了不同温度的热处理。在浸出试验中使用了各种洗脱液来检测热处理材料中Sr离子的浸出情况。用1 M氯化钠洗脱液仅洗出了最初吸附在纳米多孔AlBS基质中的3.43%的Sr离子,这表明将样品加热到约1100°C成功地将Sr离子捕获在纳米多孔AlBS基质中。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/14bf/11405862/feb00c003511/41598_2024_72126_Fig1_HTML.jpg

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