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Total Synthesis of (±)-3-Thiaglutamate.
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Thioaminal Covalent Adaptable Networks via Thiol-Aldehyde-Amine Multicomponent Polymerization.
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Substrate Recognition by the Peptidyl-()-2-mercaptoglycine Synthase TglHI during 3-Thiaglutamate Biosynthesis.
ACS Chem Biol. 2022 Apr 15;17(4):930-940. doi: 10.1021/acschembio.2c00087. Epub 2022 Apr 1.
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Structures of the holoenzyme TglHI required for 3-thiaglutamate biosynthesis.
Structure. 2023 Oct 5;31(10):1220-1232.e5. doi: 10.1016/j.str.2023.08.004. Epub 2023 Aug 30.

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Iron‑catalyzed divergent synthesis of carbazole-based di-/triarylmethanes.
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Catalytic Markovnikov Hydrothiolation of Dehydroamino Acids: Unified Total Synthesis of Enteropeptin Sactipeptides.
J Am Chem Soc. 2025 Aug 27;147(34):30661-30673. doi: 10.1021/jacs.5c03669. Epub 2025 Aug 14.

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Total Synthesis and Stereochemical Assignment of Enteropeptin A.
J Am Chem Soc. 2024 Jul 3;146(26):17629-17635. doi: 10.1021/jacs.4c06126. Epub 2024 Jun 23.
2
Late-Stage Formation of a Sactionine Linkage Enabled by Lossen Rearrangement of Glycyl Hydroxamic Acid.
Org Lett. 2024 Jun 21;26(24):5167-5171. doi: 10.1021/acs.orglett.4c01685. Epub 2024 Jun 7.
3
Structures of the holoenzyme TglHI required for 3-thiaglutamate biosynthesis.
Structure. 2023 Oct 5;31(10):1220-1232.e5. doi: 10.1016/j.str.2023.08.004. Epub 2023 Aug 30.
4
Biosynthesis of 3-thia-α-amino acids on a carrier peptide.
Proc Natl Acad Sci U S A. 2022 Jul 19;119(29):e2205285119. doi: 10.1073/pnas.2205285119. Epub 2022 Jul 5.
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Synthesis of Amino Acid α-Thioethers and Late-Stage Incorporation into Peptides.
Org Lett. 2022 May 27;24(20):3680-3685. doi: 10.1021/acs.orglett.2c01297. Epub 2022 May 16.
6
Substrate Recognition by the Peptidyl-()-2-mercaptoglycine Synthase TglHI during 3-Thiaglutamate Biosynthesis.
ACS Chem Biol. 2022 Apr 15;17(4):930-940. doi: 10.1021/acschembio.2c00087. Epub 2022 Apr 1.
7
Preparation of Thioaminals in Water.
Molecules. 2022 Mar 3;27(5):1673. doi: 10.3390/molecules27051673.
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A biosynthetic pathway to aromatic amines that uses glycyl-tRNA as nitrogen donor.
Nat Chem. 2022 Jan;14(1):71-77. doi: 10.1038/s41557-021-00802-2. Epub 2021 Nov 1.
9
Three-component radical homo Mannich reaction.
Nat Commun. 2021 Feb 12;12(1):1006. doi: 10.1038/s41467-021-21303-3.

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