Lee Dae-Gyun, Kim Min-Woo, Ku Min-Jong, Bae Yoon-Ho, Kim Kang-Min, Kim Gyeong-Min, Jeon Chung-Hwan
Korea Institute of Energy Research (KIER), 152, Gajeong-ro, Yuseong-gu, Daejeon, 34129, Republic of Korea.
School of Mechanical Engineering, Pusan Nat'l Univ., 2, Busandaehak-ro 63beon-gil, Geumjeong-gu, Busan, 46241, Republic of Korea.
Heliyon. 2024 Aug 30;10(17):e36238. doi: 10.1016/j.heliyon.2024.e36238. eCollection 2024 Sep 15.
Currently, the steelmaking process uses a pulverized coal injection (PCI) system that serves as the heat source and reductant for ironmaking (blast furnace and FINEX) where system uses expensive high-grade coal and high operating costs. Hydrogen steelmaking is currently being developed to achieve carbon-free operation. To achieve a soft-landing during this phase of rapid change, the use of biomass and inexpensive, thermal coal, and coke dust is necessary. Research on their combustion characteristics is necessary to apply these alternative fuels to PCI. Therefore, this study analyzed the combustion characteristics of ignition delay, devolatilization, and char combustion using a laminar flow reactor visualization equipment that simulates blast furnace (BF) and FINEX PCI tuyere, using flame image data processing. The ignition time were generally longer in BF than in FINEX, and the char combustion length and time also showed the same trend due to the high oxygen rate which indicate under 2 ms on ignition delay, under 16 ms on char combustion. Also, the volatile cloud was qualitatively shown in the image to be highest in thermal coal and biomass with high volatile matter. Based on the correlation and theoretical calculation with proximate analysis and the results, ignition delay time had a combined effect of volatile matter and moisture except coke dust, and char combustion time affected unburned carbon. The combustion chemical characteristics were discussed with chemical percolation devolatilization (CPD) model parameter. Through SEM image and BET analysis, the surface area has been increased more than 10 times after combustion. Consequently, the biomass and high moisture thermal coal could cofired within 10 % and coke dust could be cofired within 9 %, respectively.
目前,炼钢过程使用喷吹煤粉(PCI)系统,该系统作为炼铁(高炉和熔融还原炼铁法)的热源和还原剂,其中该系统使用昂贵的优质煤且运营成本高。目前正在开发氢炼钢以实现无碳运行。为了在这一快速变化阶段实现平稳过渡,有必要使用生物质、廉价动力煤和焦粉。对它们的燃烧特性进行研究,以便将这些替代燃料应用于喷吹煤粉工艺。因此,本研究使用层流反应器可视化设备模拟高炉(BF)和熔融还原炼铁法喷吹煤粉风口,通过火焰图像数据处理,分析了点火延迟、挥发分释放和焦炭燃烧的燃烧特性。高炉中的点火时间通常比熔融还原炼铁法中的更长,由于高氧含量,焦炭燃烧长度和时间也呈现相同趋势,表明点火延迟低于2毫秒,焦炭燃烧低于16毫秒。此外,图像定性显示,动力煤和生物质中挥发物含量高,挥发云最高。基于与近似分析的相关性和理论计算以及结果,除焦粉外,点火延迟时间受挥发物和水分的综合影响,焦炭燃烧时间影响未燃碳。用化学渗流挥发分(CPD)模型参数讨论了燃烧化学特性。通过扫描电子显微镜(SEM)图像和比表面积(BET)分析,燃烧后表面积增加了10倍以上。因此,生物质和高水分动力煤的共燃率可分别达到10%以内,焦粉的共燃率可达到9%以内。