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用于易腐水果的壳聚糖-没食子酸共轭可食用涂膜

Chitosan-gallic acid conjugate edible coating film for perishable fruits.

作者信息

Lee Cho Rok, Lee Su Jin, Kim Tae In, Chathuranga Kiramage, Lee Jong Soo, Kim Sangsik, Kim Min Hee, Park Won Ho

机构信息

Department of Organic Materials Engineering, Chungnam National University, Daejeon 34134, South Korea.

Department of Veterinary Microbiology, College of Veterinary Medicine, Chungnam National University, Daejeon 34134, South Korea.

出版信息

Food Chem. 2025 Jan 15;463(Pt 2):141322. doi: 10.1016/j.foodchem.2024.141322. Epub 2024 Sep 16.

Abstract

Approximately 30 % of global agricultural land is used to produce food that is ultimately lost or wasted, making it imperative to explore strategies for mitigating this waste. This study explored the potential of chitosan (CS) derivatives as edible coatings to extend food shelf life. Although soluble CS derivatives such as glycol CS are suitable coatings, their antimicrobial properties often diminish with increased solubility. To address this issue, gallic acid (GA), a polyphenol, was conjugated with CS using 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide/N-hydroxysuccinimide (EDC/NHS) chemistry to create edible coating solutions. The resulting CS-GA films exhibited remarkable solubility, mechanical strength, UV-blocking properties, and superior antioxidant and antimicrobial properties. Furthermore, these films exhibited a high affinity for hydrophobic fruit surfaces while also facilitating easy washing, making them an alternative for consumers who are averse to film-coated products. The CS-GA-coated fruits exhibited minimal surface spoilage, decreased mass loss, and increased firmness. Therefore, these CS-GA conjugate coatings hold significant potential as eco-friendly, edible, and washable food packaging coatings.

摘要

全球约30%的农业用地用于生产最终会损失或浪费的食物,因此探索减少此类浪费的策略势在必行。本研究探讨了壳聚糖(CS)衍生物作为可食用涂层以延长食品保质期的潜力。尽管诸如乙二醇化壳聚糖等可溶性CS衍生物是合适的涂层,但其抗菌性能常常随着溶解度的增加而减弱。为解决这一问题,使用1-乙基-3-(3-二甲基氨基丙基)碳二亚胺/ N-羟基琥珀酰亚胺(EDC/NHS)化学方法将多酚没食子酸(GA)与CS结合,以制备可食用涂层溶液。所得的CS-GA薄膜表现出显著的溶解性、机械强度、紫外线阻隔性能以及优异的抗氧化和抗菌性能。此外,这些薄膜对疏水性水果表面具有高亲和力,同时便于清洗,对于不喜欢薄膜涂层产品的消费者来说是一种替代品。涂有CS-GA的水果表面腐败极少,质量损失减少,硬度增加。因此,这些CS-GA共轭涂层作为环保、可食用且可清洗的食品包装涂层具有巨大潜力。

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